A 3-D porous nanostructure would have a balance of strength, toughness and ability to transfer heat that could benefit, nanoelectronics, gas storage and composite materials that perform multiple functions, according to engineers at Rice Univ. The researchers made this prediction by using computer simulations to create a series of 3-D prototypes with boron nitride, a chemical compound made of boron and nitrogen atoms.
Together with teams from Finland and Japan, physicists from the Univ. of Basel in Switzerland were able to place 20 single bromine atoms on a fully insulated surface at room temperature to form the smallest “Swiss cross” ever created. The effort is a breakthrough because the fabrication of artificial structures on an insulator at room temperature is difficult. It is largest number of atomic manipulations ever achieved at room temperature.
Lithium-ion batteries could benefit from a theoretical model created at Rice Univ. and Lawrence Livermore National Laboratory that predicts how carbon components will perform as electrodes. The model is based on intrinsic electronic characteristics of materials used as battery anodes. These include the material’s quantum capacitance and the material’s absolute Fermi level.
The discovery of buckyballs helped usher in the nanotechnology era. Now, researchers from Brown Univ. and colleagues from China have shown that boron, carbon’s neighbor on the periodic table, can form a cage-like molecule similar to the buckyball. Until now, such a boron structure had only been a theoretical speculation.
Marilyn Minus, a materials expert and assistant professor at Northeastern Univ., is exploring directed self-assembly methods using carbon nanotubes and polymer solutions. So far, she’s used the approach to develop a polymer composite material that is stronger than Kevlar yet much lighter and less expensive. Minus is now expanding this work to incorporate more polymer classes: flame retardant materials and biological molecules.
Rutgers Univ. researchers have developed a technology that could overcome a major cost barrier to make clean-burning hydrogen fuel. The new catalyst is based on carbon nanotubes and may rival cost-prohibitive platinum for reactions that split water into hydrogen and oxygen.
In the movie “Terminator 2,” the shape-shifting T-1000 robot morphs into a liquid state to squeeze through tight spaces or to repair itself when harmed. Now a phase-changing material built from wax and foam, and capable of switching between hard and soft states, could allow even low-cost robots to perform the same feat.
The addition of elements to the surface of graphene can modify the material’s physical and chemical properties, potentially extending the range of possible applications. Recently performed theoretical calculations at RIKEN in Japan show that the addition of oxygen to graphene on copper substrates results in enhanced functionalization. The resulting structure, known as an enolate, make support applications that require catalytic response.
Perovskites continue to entice materials scientists with their mix of conductivity, ferroelectricity, ferromagnetism, and catalytic activity. In recent years, scientists realized that they could vastly improve the properties of perovskites by assembling them into thin films, but nobody knew the reason why. But studying the chemistry layer-by-layer, experts working with x-ray beamline at Argonne National Laboratory are getting close.
The editors of R&D Magazine have announced the winners of the 52nd annual R&D 100 Awards, an international competition that recognizes the 100 most technologically significant products introduced into the marketplace over the past year. The R&D 100 Awards recognize excellence across a wide range of industries...
Scientists at Stanford Univ. and the Dept. of Energy (DOE)’s SLAC National Accelerator Laboratory have found a way to estimate uncertainties in computer calculations that are widely used to speed the search for new materials for industry, electronics, energy, drug design and a host of other applications. The technique, reported in Science, should quickly be adopted in studies that produce some 30,000 scientific papers per year.
Introducing R&D Magazine's 2014 R&D 100 Award winners. The 2014 R&D 100 Award Winners are listed below in alphabetical order by the name of the primary developer company.
A research group based in Japan has developed a new methodology that can easily and precisely control the timing, structure, and functions in the self-assembly of pi-conjugated molecules, which are an important enabling building block in the field of organic electronics. One of the key steps is keeping these molecules in a liquid form at room temperature.
First developed five years ago at Rice Univ., silicon oxide memories are a type of two-terminal, “resistive random-access memory” (RRAM) technology that beats flash memory’s data density by a factor of 50. At Rice, the laboratory of chemist and 2013 R&D Magazine Scientist of the Year James Tour has recently developed a new version of RRAM that Tour believes outperforms more than a dozen competing versions.
A team in the U.K. has found that by sandwiching a 7-nm thick layer of a phase change material between two layers of a transparent electrode they could use a tiny current to “draw” images within the sandwich “stack”. The discovery could make it possible to create pixels just a few hundred nanometers across and pave the way for extremely high-resolution and low-energy thin, flexible displays.
Too cool and faint, many objects in the universe are impossible to detect with visible light. Now a Northwestern Univ. team has refined a new technology that could make these colder objects more visible, paving the way for enhanced exploration of deep space. The new technology uses a type II superlattice material called indium arsenide/indium arsenide antimonide (InAs/InAsSb).
Geckos and spiders seem to be able to sit still forever upside down. But sooner or later the grip is lost, no matter how little force is acting on it. Engineers, using scanning electron microscopy, have recently demonstrated why this is so by showing how heat, and the subsequent movement of molecules at the nanoscale, eventually force loss of adhesion.
When a superconductor is exposed to a magnetic field, a surface current creates a magnetic field that cancels the field inside the superconductor. This phenomenon, known as the Meissner-Ochsenfeld effect, was first observed in 1933. In a research first, scientists have succeeded in measuring an analogue of the Meissner effect in an optical crystal with ultracold atoms. This validates theoretical predictions dating back more than 20 years.
A new type of catalyst, based on carbon, can facilitate two opposite reactions: electrolysis of water and combustion of hydrogen with oxygen. This bi-functionality, developed by researchers in Germany, is made possible from its construction: manganese-oxide or cobalt-oxide nanoparticles which are embedded in specially modified carbon, then integrated with nitrogen atoms in specific positions.
Researchers at the Univ. of California, Riverside have used a quartz-rich material to fabricate a lithium-ion battery that outperforms the current industry standard by three times. This key material? Sand. Through a heating process with salt and magnesium, the scientists created a porous nano-silicon sponge that greatly increases active surface area.
With a chemical “trick”, scientists in Germany have succeeded in isolating a stable gold carbene complex. Experts have been proposing gold carbenes as essential short-lived intermediates in catalytic reactions, but they elude study because of their high reactivity. Chemist Prof. Dr. Bernd F. Straub and his team are the first to have created the basis for directly examining the otherwise unstable gold-carbon double bond.
Overturning conventional wisdom stretching all the way to Leonardo da Vinci, new research from Israel shows that how things break and how things slide are closely interrelated. The breakthrough study marks an important advance in understanding friction and fracture, with implications for describing the mechanics that drive earthquakes.
Researchers at Pacific Northwest National Laboratory have developed a porous material to replace the graphite traditionally used in a battery's electrodes. Made from silicon, which has more than 10 times the energy storage capacity of graphite, the sponge-like material can help lithium-ion batteries store more energy and run longer on a single charge.
An international research collaboration has designed a miniscule cooling element that uses spin waves to transport heat in electrical insulators. Although physicists have used spin for cooling purposes before, this is the first time that they have successfully done this in insulating materials. The cooling element could be used to dissipate heat in the increasingly smaller electrical components of computer chips.
For the last century, the concept of crystals has been a mainstay of solid-state physics. Crystals are paragons of order; crystalline materials are defined by the repeating patterns their constituent atoms and molecules make. Now physicists have evidence that a new concept should undergird our understanding of most materials: the anticrystal, a theoretical solid that is completely disordered.