Amid concerns over the potential health effects of existing flame retardants for home furniture, fabrics and other material, are reporting development of an “exceptionally” effective new retardant that appears safer and more environmentally friendly. The key is a nanocoating made with a relatively benign polymer that creates a “gas blanket,” preventing oxygen from fueling a fire.
Cells are the basic unit of life and are separated from the outside world by a thin organic membrane. A major function of this membrane is to allow certain molecules to enter or leave the cell whilst other molecules are blocked from the cell interior. This allows metabolic processes to take place. Controlling membrane permeability is therefore a key challenge when building artificial cells in the form of enclosed chemical systems.
A polymer thin film solar cell (PSC) produces electricity from sunlight by the photovoltaic effect. Though light and inexpensive, PSCs currently suffer from a lack of enough efficiency for large scale applications and they also have stability problems. Researches in Korea have designed and added multi-positional silica-coated silver nanoparticles that have greatly improved stability and performance of these cells.
A team led by Lawrence Berkeley National Laboratory Materials Sciences Division’s Jeffrey Urban and Rachel Segalman have discovered highly conductive polymer behavior occurring at a polymer/nanocrystal interface. The composite organic/inorganic material is a thermoelectric—a material capable of converting heat into electricity—and has a higher performance than either of its constituent materials.
Methanol to formaldehyde: This reaction is the starting point for the synthesis of many everyday plastics. Using catalysts made of gold particles, however, formaldehyde could be produced without the environmentally hazardous waste generated in conventional methods. But just how a gold catalyst could work has only recently been discovered by researchers.
Coating medical supplies with an antimicrobial material is one approach that bioengineers are using to combat the increasing spread of multidrug-resistant bacteria. A research team in Singapore has now developed a highly effective antimicrobial coating based on cationic polymers. The coating can be applied to medical equipment, such as catheters.
U.S. Naval Research Laboratory scientists have developed a second-generation, cost-effective polyetheretherketone (PEEK)-like phthalonitrile-resin demonstrating superior high-temperature and flammability properties for use in marine, aerospace, and domestic applications. The resin can be used to make composite components by established industrial methods and automated composite manufacturing techniques.
A new chemical process can transform waste sulfur into a lightweight plastic that may improve batteries for electric cars, reports a University of Arizona-led team. The new plastic has other potential uses, including optical uses. The team has successfully used the new plastic to make lithium-sulfur batteries.
The accidental discovery by Chemical Engineering Professor Tim Bender and postdoctoral fellow Benoit Lessard of an unexpected side product of polymer synthesis could have implications for the manufacture of commercial polymers used in sealants, adhesives, toys, and even medical implants, the researchers say.
Japan-based Teijin Limited has developed technology to significantly enhance the heat and impact resistance of PLANEXT, the company’s high-performance bioplastic. The technology modifies the molecular design of PLANEXT to achieve greatly improved heat resistance with a glass-transition temperature of 120 C, as well as superior resistance to impact.
Ditch the 3D glasses. Thanks to a simple plastic filter, mobile device users can now view unprecedented, distortion-free, brilliant 3D content with the naked eye. This latest innovation from researchers in Singapore is the first ever glasses-free 3D accessory that can display content in both portrait and landscape mode, and measures less than 0.1 mm in thickness.
Scientists may soon be able to turn to one of the most powerful forces in biology—evolution—to help in their quest to develop new synthetic polymers. As described in a recent paper, a team of Harvard University researchers has developed a new method to create synthetic polymers using the coding of genetic material. The method may eventually be used to evolve synthetic polymers with new or improved properties such as the ability to serve as catalysts in chemical reactions or enhanced therapeutic potential.
Chemical companies each year churn out billions of tons of acrylate, a valuable commodity chemical involved in the manufacture of everything from polyester cloth to disposable diapers. It is usually made by heating propylene, a compound derived from crude oil. Researchers at Brown and Yale universities have demonstrated a new “enabling technology” that could instead use excess carbon dioxide to produce acrylate.
Researchers from North Carolina State University have come up with a low-cost way to enhance a polymer called MEH-PPV's ability to confine light, advancing efforts to use the material to convert electricity into laser light for use in photonic devices.
MEH-PPV is a low-cost polymer that can be integrated with silicon chips, and researchers have sought to use it to convert electricity into laser light for use in photonic devices. However, attempts to do this have failed because the amount of electricity needed to generate laser light in MEH-PPV was so high that it caused the material to degrade. Researchers have recently come up with a low-cost way to enhance MEH-PPV’s ability to confine light, protecting the material.
Germany-based company AMSilk has produced the world’s first competitive man-made spider silk fiber, called Biosteel, which is made entirely from recombinant silk proteins. Biosteel has mechanical properties similar to that of natural spider silk when comparing toughness, a measure indicating the kinetic energy absorbed before the fiber breaks.
Until recently, there has been no systematic way of evaluating how different anti-fog coatings perform under real-world conditions. A team of MIT researchers has developed such a testing method, and used it to find a coating that outperforms others not only in preventing foggy buildups, but also in maintaining good optical properties without distortion.
Pharmaceutical residues in water can pose a danger to humans. Filtration is often very difficult as these trace substances, which are soluble in water, are so minute. Newly-developed double switchable membranes could make it possible to filter these molecules, as well as other biomolecules such as proteins and nucleic acids. The new membranes can reduce or enlarge pore size through changes in temperature and pH value.
Engineers and scientists from the University of Sheffield have pioneered a new technique to analyze PCBM, a material used in polymer photovoltaic cells, obtaining details of the structure of the material which will be vital to improving the cell's efficiency.
When gluing things together, both surfaces usually need to be dry. Gluing wet surfaces or surfaces under water is a challenge. Korean scientists have now introduced a completely new concept. They were able to achieve reversible underwater adhesion by using supramolecular "Velcro".
A research team in Austria has developed an entirely new way of capturing images based on a flat, flexible, transparent, and potentially disposable polymer sheet. The new imager, which resembles a flexible plastic film, uses fluorescent particles to capture incoming light and channel a portion of it to an array of sensors framing the sheet. With no electronics or internal components, the imager’s elegant design makes it ideal for a new breed of imaging technologies.
Researchers at the Massachusetts Institute of Technology have pioneered a new method for producing polymer gels with tailored mechanical properties. The approach, which depends on the use of ultraviolet to break chemical bonds and prime them for new connections, could be used to make new materials that physically grow towards a light source in order to optimize their properties.
Traditionally, carbon fibers are made by “carbonizing” a polymer called poly-acrylonitrile, or PAN, by spinning it into a fiber and heating to form a homogenous carbons structure. Since its invention, improvement have been incremental, and version made with 100% carbon nanotubes are extremely expensive. A researcher at Northeastern University is working on a much cheaper, and stronger, alternative.
Northwestern University graduate student Jonathan Barnes had a hunch for creating an exotic new chemical compound, and his idea that the force of love is stronger than hate proved correct. He and his colleagues are the first to permanently interlock two identical tetracationic rings that normally are repelled by each other. Many experts had said it couldn't be done.
Bacterial biofilms, which diseased groupings of cells found in 80% of infections, are a significant health hazard and one of the biggest headaches for hospitals and their constant battle against disease. Researchers from IBM, with the help of scientists in Singapore, revealed today a synthetic antimicrobial hydrogel that can break through diseased biofilms and completely eradicate drug-resistant bacteria upon contact. It is the first hydrogel to be biodegradable, biocompatible, and non-toxic.