A new concept in metallic alloy design called “high-entropy alloys” has yielded a multiple-element material that tests out as one of the toughest on record. But, unlike most materials, the toughness as well as the strength and ductility of this alloy, which contains five major elements, actually improves at cryogenic temperatures.
When metallic lithium forms and deposits during the charging process in a lithium-ion battery, it can lead to a reduced battery lifespan and even short circuits. Using neutron beams, scientists have now peered into the inner workings of a functioning battery without destroying it. In the process, they have resolved this so-called lithium plating mystery.
The field of astrophysics has a stubborn problem and it’s called lithium. The quantities of lithium predicted to have resulted from the Big Bang are not actually present in stars. But the calculations are correct, a fact which has now been confirmed for the first time in experiments conducted at the underground laboratory in the Gran Sasso mountain in Italy.
Sensors made with copper could be cheap, light, flexible and highly conductive. Making such concepts affordable enough for general use remains a challenge but a new way of working with copper nanowires and a PVA “nano glue” could be a game-changer. Engineers in Australia have found a way of making flexible copper conductors cost-effective enough for commercial applications.
For tiny fractions of a second, when illuminated by a laser pulse, quartz glass can take on metallic properties. The phenomenon, recently revealed by large-scale computer simulations, frees electrons, allowing quartz to become opaque and conduct electricity. The effect could be used to build logical switches which are much faster than today’s microelectronics.
In a recent paper, a team at Stanford Univ. which includes materials science expert Yi Cui and 2011 R&D Magazine Scientist of the Year Steven Chu report that they have taken a big step toward accomplishing what battery designers have been trying to do for decades: design a pure lithium anode.
By colliding ultra-small gold particles with a surface and analyzing the resulting fragments, a trio of scientists at Pacific Northwest National Laboratory discovered how and why the particles break. This information is important for controlling the synthesis of these tiny building blocks that are of interest to catalysis, energy conversion and storage, and chemical sensing.
The yield so far is small, but chemists at the Univ. of Oregon have developed a low-energy, solution-based mineral substitution process to make a precursor to transparent thin films. The inorganic process is a new approach to transmetalation, in which individual atoms of one metal complex are individually substituted in water. The innovation could find use in electronics and alternative energy devices.
A new type of catalyst, based on carbon, can facilitate two opposite reactions: electrolysis of water and combustion of hydrogen with oxygen. This bi-functionality, developed by researchers in Germany, is made possible from its construction: manganese-oxide or cobalt-oxide nanoparticles which are embedded in specially modified carbon, then integrated with nitrogen atoms in specific positions.
With a chemical “trick”, scientists in Germany have succeeded in isolating a stable gold carbene complex. Experts have been proposing gold carbenes as essential short-lived intermediates in catalytic reactions, but they elude study because of their high reactivity. Chemist Prof. Dr. Bernd F. Straub and his team are the first to have created the basis for directly examining the otherwise unstable gold-carbon double bond.
Iron is present in tiny concentrations in seawater, on the order of a few billionths of a gram in a liter. However, its availability in seawater can have a profound effect on phytoplankton growth and, consequently, the Earth's carbon cycle. In recent research, an assessment was made of the various sources of dissolved iron in the north Atlantic Ocean and surprising discoveries were made about their origins.
Ancient Japanese gold leaf artists were truly masters of their craft. An analysis of six of these Japanese paper screens show that these artifacts are gilded with gold leaf that was hand-beaten to the nanometer scale. The study was able to prove this without any damage to the screens through the use of x-ray fluorescence spectroscopy.
Titanium dioxide nanoparticles show great promise as optical encapsulants or fillers for tunable refractive index coatings. However, they've been largely shunned because they’ve been difficult and expensive to make. Scientists at Sandia National Laboratories have now come up with an inexpensive way to synthesize properly sized titanium dioxide nanoparticles and is seeking partners who can demonstrate the process at industrial scale.
A breakthrough has been made in identifying the origin of superconductivity in high-temperature superconductors, which has puzzled researchers for the past three decades. Researchers in the U.K. have found that ripples of electrons, known as charge density waves or charge order, create twisted ‘pockets’ of electrons in these materials, from which superconductivity emerges.
A new nanoparticle platform developed in California increases the efficiency of drug delivery and allows excess particles to be washed away. A simple etching technique using biocompatible chemicals rapidly disassembles and removes the silver nanoparticles outside living cells. This method leaves only the intact nanoparticles for imaging or quantification, revealing which cells have been targeted and how much each cell internalized.
Surface catalysts are notoriously difficult to study mechanistically, but scientists at two universities have recently shown how to get real-time reaction information from silver nanocatalysts that have long frustrated attempts to describe their kinetic behavior in detail. The key to the team's success was bridging a size gap that had represented a wide chasm to researchers in the past.
Rensselaer Polytechnic Institute scientists have developed a method that can predict how subjecting metals to severe pressure can lower their electrical resistance. The finding which involved theoretical predictions, use of a supercomputer, and equipment capable of exerting pressures up to 40,000 atmospheres, could have applications in computer chips and other materials that could benefit from specific electrical resistance.
Research published in the Proceedings of the National Academy of Sciences makes it possible to predict how subjecting metals to severe pressure can lower their electrical resistance, a finding that could have applications in computer chips and other materials that could benefit from specific electrical resistance.
Thermal systems use heat to produce cold, and vice versa. The human body demonstrates this function when it perspires, but what is lacking for devices that operate on this principle are materials capable of sufficiently discharging the water vapor quickly. Metal organic frameworks (MOFs) are well suited to this task. Researchers have built a new 3-D porous MOF from metals and organic linkers that substantially increases water absorption.
Using a doped-graphene matrix to slow down and then trap atoms of the precious metal osmium, researchers in the U.K. have shown the ability to control and quantify the growth of metal-crystals. When the trapped atoms come into contact with further osmium atoms they bind together, eventually growing into 3-D metal-crystals. They have called this new technique nanocrystallometry.
Researchers in Japan have developed a new nickel catalyst with a “kabuto-like” structure that was found to catalyze the cross-coupling reaction between carbonyl compounds and readily available phenol derivatives, to form arylketones, which are found in many biologically active compounds. A kabuto is a helmet worn by Japanese samurai.
An international team of researchers have figured out a new way of storing and releasing hydrogen by making a unique crystal phase of a material containing lithium, boron and the key ingredient, hydrogen. To check how they could get the hydrogen back out of the material, the scientists heated it and found that it released hydrogen easily, quickly and only traces of unwanted by-products.
Vanadium dioxide is called a "wacky oxide" because it transitions between a conducting metal and an insulating semiconductor and with the addition of heat or electrical current. A device created by Penn State engineers uses a thin film of vanadium oxide on a titanium dioxide substrate to create an oscillating switch that could form the basis of a computational device that uses a fraction of the energy necessary for today’s computers.
While flexible gadgets such as “electronic skin” and roll-up touch screens are moving ever closer to reality, their would-be power sources are either too wimpy or too stiff. But that’s changing fast. Scientists have developed a new device that’s far thinner than paper, can flex and bend, and store enough energy to provide critical back-up power for portable electronics.
Northwestern Univ. researchers are the first to develop a new solar cell with good efficiency that uses tin instead of lead perovskite as the harvester of light. The low-cost, environmentally friendly solar cell can be made easily using "bench" chemistry, with no fancy equipment or hazardous materials.