A team of Caltech chemists has discovered a method for producing a group of silicon-containing organic chemicals without relying on expensive precious metal catalysts. Instead, the new technique uses as a catalyst a cheap, abundant chemical that is commonly found in chemistry labs around the world, potassium tert-butoxide, to help create a host of products ranging from new medicines to advanced materials.
When a metal tube lines an oil well thousands of feet below the surface of the ocean, that metal had better be solid and reliable. Unfortunately, the environment in such deep wells is often rich in hydrogen, a gas that can penetrate high-tech alloys and make them brittle, making fractures and leaks more likely. Now researchers have figured which characteristics of a metal structure foster this embrittlement in the presence of hydrogen.
While the mysterious, unseen forces magnets project are now (mostly) well understood, they can still occasionally surprise us. For instance, thin films of cobalt have been observed to spontaneously switch their poles: something that typically doesn’t happen in the absence of an external magnetic field. Physicists at NIST and the Univ. of Maryland have measured this phenomenon on the largest scale yet.
Researchers at Virginia Commonwealth Univ. and universities in China and Japan have discovered a new structural variant of carbon called "penta-graphene", a very thin sheet of pure carbon that has a unique structure inspired by a pentagonal pattern of tiles found paving the streets of Cairo.
Far from being a defect, a winding thread of odd rings at the border of two sheets of graphene has qualities that may prove valuable to manufacturers, according to Rice Univ. scientists. Graphene rarely appears as a perfect lattice of chicken wire-like six-atom rings. When grown via chemical vapor deposition, it usually consists of “domains,” or separately grown sheets that bloom outward from hot catalysts until they meet up.
The editors of R&D Magazine are looking for speakers to participate in a webinar on “Using Multiple Materials in 3D Printing.” Candidates are asked to give a 15-min PowerPoint-based talk over the phone on their experiences in fabricating 3D printed products using multiple materials or developing the processes and/or technologies to accomplish this.
Efficiency is big in the tiny world of thermoelectric nanowires. Researchers at Sandia National Laboratories say better materials and manufacturing techniques for the nanowires could allow carmakers to harvest power from the heat wasted by exhaust systems or lead to more efficient devices to cool computer chips.
If you can’t find the ideal material, then design a new one. Northwestern Univ.’s James Rondinelli uses quantum mechanical calculations to predict and design the properties of new materials by working at the atom-level. His group’s latest achievement is the discovery of a novel way to control the electronic band gap in complex oxide materials without changing the material’s overall composition.
Engineers are shining new light on an emerging family of solar-absorbing materials that could clear the way for cheaper and more efficient solar panels and LEDs. The materials, called perovskites, are particularly good at absorbing visible light, but had never been studied in their purest form: as perfect single crystals.
Imagine eyeglasses that can go quickly from clear to shaded and back again when you want them to, rather than passively in response to changes in light. Scientists report a major step toward that goal, which could benefit pilots, security guards and others who need such control, in ACS Applied Materials & Interfaces.
In Science, Los Alamos National Laboratory researchers reveal a new solution-based hot-casting technique that allows growth of highly efficient and reproducible solar cells from large-area perovskite crystals. The researchers fabricated planar solar cells from pervoskite materials with large crystalline grains that had efficiencies approaching 18%.
A potential avenue to quantum computing currently generating quite the buzz in the high-tech industry is “valleytronics,” in which information is coded based on the wavelike motion of electrons moving through certain 2-D semiconductors. Now, a promising new pathway to valleytronic technology has been uncovered by researchers with the Lawrence Berkeley National Laboratory.
Friction impacts motion, hence the need to control friction forces. Currently, this is accomplished by mechanistic means or lubrication, but experiments conducted by researchers at Oak Ridge National Laboratory have uncovered a way of controlling friction on ionic surfaces at the nanoscale using electrical stimulation and ambient water vapor.
Nature packs away carbon in chalk, shells and rocks made by marine organisms that crystallize calcium carbonate. Now, research suggests that the soft, organic scaffolds in which such crystals form guide crystallization by soaking up the calcium like an "ion sponge". Understanding the process better may help researchers develop advanced materials for energy and environmental uses, such as for removing carbon dioxide from the atmosphere.
Using one of the largest supercomputers in the world, a team of researchers led by the Univ. of Minnesota has identified potential materials that could improve the production of ethanol and petroleum products. The discovery could lead to major efficiencies and cost savings in these industries. The Univ. of Minnesota has two patents pending on the research and hopes to license these technologies.
Graphene has many desirable properties. Magnetism alas is not one of them. Magnetism can be induced in graphene by doping it with magnetic impurities, but this doping tends to disrupt graphene's electronic properties. Now a team of physicists at the Univ. of California, Riverside has found an ingenious way to induce magnetism in graphene while also preserving graphene's electronic properties.
A team of chemists at Nagoya Univ. has synthesized novel transition metal-complexed cycloparaphenylenes (CPPs) that enable selective monofunctionalization of CPPs for the first time, opening doors to the construction of unprecedented nanocarbons. The team has synthesized novel CPP chromium complexes and demonstrated their utility in obtaining monofunctionalized CPPs, which could be useful for making carbon nanotubes.
Researchers in Japan revealed that improvements should soon be expected in the manufacture of transistors that can be used, for example, to make flexible, paper-thin computer screens. The scientists reviewed the latest developments in research on photoactive organic field-effect transistors, devices that incorporate organic semiconductors, amplify weak electronic signals and either emit or receive light.
Scientists at the Univ. of Liverpool have controlled the structure of a material to simultaneously generate both magnetization and electrical polarization, an advance which has potential applications in information storage and processing. The researchers demonstrated that it's possible to unlock these properties in a material which initially displayed neither by making designed changes to its structure.
Theoretical physicists at Rice Univ. are living on the edge as they study the astounding properties of graphene. In a new study, they figure out how researchers can fracture graphene nanoribbons to get the edges they need for applications. New research shows it should be possible to control the edge properties of graphene nanoribbons by controlling the conditions under which the nanoribbons are pulled apart.
With its high electrical conductivity and optical transparency, indium tin oxide is one of the most widely used materials for touchscreens, plasma displays and flexible electronics. But its rapidly escalating price has forced the electronics industry to search for other alternatives. One potential and more cost-effective alternative is a film made with silver nanowires embedded in flexible polymers.
A research team has developed a new technique for determining the role that a material’s structure has on the efficiency of organic solar cells, which are candidates for low-cost, next-generation solar power. The researchers have used the technique to determine that materials with a highly organized structure at the nanoscale are not more efficient at creating free electrons than poorly organized structures.
One of the reasons solar cells are not used more widely is cost: The materials used to make them most efficient are expensive. Engineers are exploring ways to print solar cells from inks, but the devices don’t work as well. A team of engineers has developed a technique to increase the performance and electrical conductivity of thin films that make up these materials using nanotechnology.
Scientists have identified synthetic materials that may purify ethanol more efficiently and greatly improve the separation of long-chain hydrocarbons in petroleum refining. The results show that predictive modeling of synthetic zeolites is highly effective and can help solve some of the most challenging problems facing industries that require efficient ways to separate or catalyze materials.
Sound waves passing through the air, objects that break a body of water and cause ripples or shockwaves from earthquakes all are considered “elastic” waves. These waves travel at the surface or through a material without causing any permanent changes to the substance’s makeup. Now, researchers have developed a material that has the ability to control these waves.