Graphene, a material that consists of a lattice of carbon atoms, one atom thick, is widely touted as being the most electrically conductive material ever studied. However, not all graphene is the same. With so few atoms comprising the entirety of the material, the arrangement of each one has an impact on its overall function.
The yield so far is small, but chemists at the Univ. of Oregon have developed a low-energy, solution-based mineral substitution process to make a precursor to transparent thin films. The inorganic process is a new approach to transmetalation, in which individual atoms of one metal complex are individually substituted in water. The innovation could find use in electronics and alternative energy devices.
Applying just the right amount of tension to a chain of carbon atoms can turn it from a metallic conductor to an insulator, according to Rice Univ. scientists. Stretching the material known as carbyne by just 3% can begin to change its properties in ways that engineers might find useful for mechanically activated nanoscale electronics and optics.
A Univ. of Alabama start-up company, 525 Solutions, has received about $1.5 million from the federal government to refine an invention to extract uranium from the ocean for use as fuel. It is an adsorbent, biodegradable material made from the compound chitin, which is found in crustaceans and insects. The researchers have developed transparent sheets, or mats, comprised of tiny chitin fibers, which pull uranium from the water.
One of the major road blocks to the design and development of new, more efficient solar cells may have been cleared. Researchers with the Lawrence Berkeley National Laboratory have developed the first ab initio method for characterizing the properties of “hot carriers” in semiconductors. Hot carriers are electrical charge carriers with significantly higher energy than charge carriers at thermal equilibrium.
Nearly all electronics require devices called oscillators that create precise frequencies. For nearly 100 years, these oscillators have relied upon quartz crystals to provide a frequency reference, much like a tuning fork is used as a reference to tune a piano. However, future high-end navigation systems, radar systems and even possibly tomorrow's consumer electronics will require references beyond the performance of quartz.
The common pencil squid may hold the key to a new generation of medical technologies that could communicate more directly with the human body. Materials science researchers in California have discovered that reflectin, a protein in the tentacled creature’s skin, can conduct positive electrical charges, or protons, making it a promising material for building biologically inspired devices.
A team including scientists from Spain and from IBM Research in Switzerland have published work which describes an extremely simple method to obtain high quality nanographenes from easily available organic compounds. This method is based on the reactivity of a group of molecules named arynes, which can act as "molecular glue" to paste graphene fragments together.
Scientists have designed a new self-assembling nanoparticle that targets tumors, to help doctors diagnose cancer earlier. The new nanoparticle, developed by researchers in the U.K., boosts the effectiveness of magnetic resonance imaging scanning by specifically seeking out receptors that are found in cancerous cells.
New York state is teaming with General Electric Co. and other companies on a $500 million initiative to spur high-tech manufacturing of miniature electronics, Gov. Andrew Cuomo and GE CEO Jeffrey Immelt announced Tuesday. The state will invest $135 million for the collaborative program, which will be based out of the SUNY College of Nanoscale Science and Engineering in Albany.
A 3-D porous nanostructure would have a balance of strength, toughness and ability to transfer heat that could benefit, nanoelectronics, gas storage and composite materials that perform multiple functions, according to engineers at Rice Univ. The researchers made this prediction by using computer simulations to create a series of 3-D prototypes with boron nitride, a chemical compound made of boron and nitrogen atoms.
Together with teams from Finland and Japan, physicists from the Univ. of Basel in Switzerland were able to place 20 single bromine atoms on a fully insulated surface at room temperature to form the smallest “Swiss cross” ever created. The effort is a breakthrough because the fabrication of artificial structures on an insulator at room temperature is difficult. It is largest number of atomic manipulations ever achieved at room temperature.
The discovery of buckyballs helped usher in the nanotechnology era. Now, researchers from Brown Univ. and colleagues from China have shown that boron, carbon’s neighbor on the periodic table, can form a cage-like molecule similar to the buckyball. Until now, such a boron structure had only been a theoretical speculation.
Marilyn Minus, a materials expert and assistant professor at Northeastern Univ., is exploring directed self-assembly methods using carbon nanotubes and polymer solutions. So far, she’s used the approach to develop a polymer composite material that is stronger than Kevlar yet much lighter and less expensive. Minus is now expanding this work to incorporate more polymer classes: flame retardant materials and biological molecules.
In the movie “Terminator 2,” the shape-shifting T-1000 robot morphs into a liquid state to squeeze through tight spaces or to repair itself when harmed. Now a phase-changing material built from wax and foam, and capable of switching between hard and soft states, could allow even low-cost robots to perform the same feat.
The addition of elements to the surface of graphene can modify the material’s physical and chemical properties, potentially extending the range of possible applications. Recently performed theoretical calculations at RIKEN in Japan show that the addition of oxygen to graphene on copper substrates results in enhanced functionalization. The resulting structure, known as an enolate, make support applications that require catalytic response.
Perovskites continue to entice materials scientists with their mix of conductivity, ferroelectricity, ferromagnetism, and catalytic activity. In recent years, scientists realized that they could vastly improve the properties of perovskites by assembling them into thin films, but nobody knew the reason why. But studying the chemistry layer-by-layer, experts working with x-ray beamline at Argonne National Laboratory are getting close.
Scientists at Stanford Univ. and the Dept. of Energy (DOE)’s SLAC National Accelerator Laboratory have found a way to estimate uncertainties in computer calculations that are widely used to speed the search for new materials for industry, electronics, energy, drug design and a host of other applications. The technique, reported in Science, should quickly be adopted in studies that produce some 30,000 scientific papers per year.
First developed five years ago at Rice Univ., silicon oxide memories are a type of two-terminal, “resistive random-access memory” (RRAM) technology that beats flash memory’s data density by a factor of 50. At Rice, the laboratory of chemist and 2013 R&D Magazine Scientist of the Year James Tour has recently developed a new version of RRAM that Tour believes outperforms more than a dozen competing versions.
A team in the U.K. has found that by sandwiching a 7-nm thick layer of a phase change material between two layers of a transparent electrode they could use a tiny current to “draw” images within the sandwich “stack”. The discovery could make it possible to create pixels just a few hundred nanometers across and pave the way for extremely high-resolution and low-energy thin, flexible displays.
Too cool and faint, many objects in the universe are impossible to detect with visible light. Now a Northwestern Univ. team has refined a new technology that could make these colder objects more visible, paving the way for enhanced exploration of deep space. The new technology uses a type II superlattice material called indium arsenide/indium arsenide antimonide (InAs/InAsSb).
A new type of catalyst, based on carbon, can facilitate two opposite reactions: electrolysis of water and combustion of hydrogen with oxygen. This bi-functionality, developed by researchers in Germany, is made possible from its construction: manganese-oxide or cobalt-oxide nanoparticles which are embedded in specially modified carbon, then integrated with nitrogen atoms in specific positions.
Researchers at the Univ. of California, Riverside have used a quartz-rich material to fabricate a lithium-ion battery that outperforms the current industry standard by three times. This key material? Sand. Through a heating process with salt and magnesium, the scientists created a porous nano-silicon sponge that greatly increases active surface area.
With a chemical “trick”, scientists in Germany have succeeded in isolating a stable gold carbene complex. Experts have been proposing gold carbenes as essential short-lived intermediates in catalytic reactions, but they elude study because of their high reactivity. Chemist Prof. Dr. Bernd F. Straub and his team are the first to have created the basis for directly examining the otherwise unstable gold-carbon double bond.
Overturning conventional wisdom stretching all the way to Leonardo da Vinci, new research from Israel shows that how things break and how things slide are closely interrelated. The breakthrough study marks an important advance in understanding friction and fracture, with implications for describing the mechanics that drive earthquakes.