New catalysts designed and investigated by Tufts Univ. have the potential to greatly reduce processing costs in future fuels, such as hydrogen. The catalysts are composed of a unique structure of single gold atoms bound by oxygen to several sodium or potassium atoms and supported on non-reactive silica materials.
Researchers at KU Leuven’s Centre for Surface Chemistry and Catalysis have successfully...
Researchers have demonstrated a new process to convert all biomass into liquid fuel, and the...
A new membrane, developed scientists in the Netherlands, can be made more or less porous “on demand”. In this way, smart switching between “open” and “closed” is possible, which opens the way to innovative applications in biosensors, chemical analysis and catalysis.
Researchers in Australia have discovered that nano-sized fragments of graphene have the ability to speed up the rate of chemical reactions. The finding is significant, say researchers, because it suggested that graphene might have potential applications in catalyzing chemical reactions of industrial importance.
Washington State Univ. (WSU) researchers have developed a new catalyst that could lead to making biofuels cheaply and more efficiently. The WSU researchers developed a mixture of two metals, iron along with a tiny amount of palladium, to serve as a catalyst to efficiently and cheaply remove oxygen.
Iron catalysts remove oxygen inexpensively, but are susceptible to rust or oxidation in biofuel production. Precious metals that resist corrosion are even less efficient at removing oxygen. But adding just a touch of palladium to the iron produces a catalyst that quickly removes oxygen atoms, easily releases the desired products, and doesn't rust, according to scientists at Pacific Northwest National Laboratory and Washington State Univ.
Swedish and Chinese researchers have recently shown how a unique nano-alloy composed of palladium nano-islands embedded in tungsten nanoparticles creates a new type of catalysts for highly efficient oxygen reduction, the most important reaction in hydrogen fuel cells. Their results are published in the scientific journal Nature Communications.
Scientists at Nanyang Technology University (NTU) in Singapore have developed a new type of lithium-ion battery in which the traditional graphite used for the anode has been replaced with a new gel material made from titanium dioxide. The new design allows the battery to endure more than 10,000 cycles, vs. about 500 recharge cycles for typical rechargeable lithium-ion batteries.
Graphene quantum dots created at Rice Univ. grab onto graphene platelets like barnacles attach themselves to the hull of a boat. But these dots enhance the properties of the mothership, making them better than platinum catalysts for certain reactions within fuel cells.
Michael Grätzel’s laboratory in Switzerland is producing hydrogen fuel from sunlight and water. By combining a pair of solar cells made with a mineral called perovskite and low cost electrodes, scientists have obtained a 12.3% conversion efficiency from solar energy to hydrogen, a record using earth-abundant materials as opposed to rare metals.
The excessive atmospheric carbon dioxide that is driving global climate change could be harnessed into a renewable energy technology that would be a win for both the environment and the economy. That is the lure of artificial photosynthesis in which the electrochemical reduction of carbon dioxide is used to produce clean, green and sustainable fuels.
When it comes to diesel engine catalysts, which are responsible for cleansing exhaust fumes, platinum has unfortunately proved to be the only viable option. This has resulted in material costs alone accounting for half of the price of a diesel catalyst. Researchers in Denmark say they have developed a new way to manufacture catalysts that may result in a 25% reduction in the use of platinum.
When metallic lithium forms and deposits during the charging process in a lithium-ion battery, it can lead to a reduced battery lifespan and even short circuits. Using neutron beams, scientists have now peered into the inner workings of a functioning battery without destroying it. In the process, they have resolved this so-called lithium plating mystery.
Scientists at Oak Ridge National Laboratory have discovered they can control chemical reactions in a new way by creating different shapes of cerium oxide, a rare-earth-based catalyst. Their finding holds potential for refining fuels, decreasing vehicle emissions, producing commodity chemicals and advancing fuel cells and chemical sensors.
A research team investigating an important cofactor in photosynthesis, a manganese-calcium complex which uses solar energy to split water into molecular oxygen, have determined the exact structure of this complex at a crucial stage in the chemical reaction. The new insights into how molecular oxygen is formed at this metal complex may provide a blueprint for synthetic systems that could store sunlight energy in chemical energy carriers.
Trying to understand the chemistry that turns plant material into the same energy-rich gasoline and diesel we put in our vehicles, researchers have discovered that water in the conversion process helps form an impurity which, in turn, slows down key chemical reactions. The study, which was reported online at the Journal of the American Chemical Society, can help improve processes that produce biofuels from plants.
A research team in Europe has achieved significantly increase in the yield of hydrogen produced by the photocatalytic splitting of water. Their breakthrough in light-driven generation of hydrogen was achieved by using a novel molecular shuttle to enhance charge-carrier transport with semiconductor nanocrystals.
A catalyst made from a foamy form of copper has vastly different electrochemical properties from catalysts made with smooth copper in reactions involving carbon dioxide, a new study shows. The research, by scientists in Brown Univ.’s Center for the Capture and Conversion of CO2, suggests that copper foams could provide a new way of converting excess CO2 into useful industrial chemicals.
North Carolina State Univ. is part of a project team that is researching and developing new catalyst technology to produce the commercially important chemicals ethylene and propylene from natural gas. The project lead, Bio2Electric, LLC, dba EcoCatalytic Technologies, is collaborating with North Carolina State Univ., among other industry partners, to develop the new catalyst technologies.
Zeolites used extensively in industry are promising catalysts that turn biomass into transportation fuels, but the activity and stability of this class of materials is challenging to understand and predict. Employing a combination of methods devised at Pacific Northwest National Laboratory and the Swiss Light Source, scientists were able to determine the distribution of aluminum ions in structural variants of zeolites.
A multi-institutional team has resolved a long-unanswered question about how two of the world’s most common substances interact. In a paper published recently in Nature Communications, an international team reported fundamental discoveries about how water reacts with metal oxides. The paper opens doors for greater understanding and control of chemical reactions in fields ranging from catalysis to geochemistry and atmospheric chemistry.
In a recent paper, a team at Stanford Univ. which includes materials science expert Yi Cui and 2011 R&D Magazine Scientist of the Year Steven Chu report that they have taken a big step toward accomplishing what battery designers have been trying to do for decades: design a pure lithium anode.
Rutgers Univ. researchers have developed a technology that could overcome a major cost barrier to make clean-burning hydrogen fuel. The new catalyst is based on carbon nanotubes and may rival cost-prohibitive platinum for reactions that split water into hydrogen and oxygen.
The addition of elements to the surface of graphene can modify the material’s physical and chemical properties, potentially extending the range of possible applications. Recently performed theoretical calculations at RIKEN in Japan show that the addition of oxygen to graphene on copper substrates results in enhanced functionalization. The resulting structure, known as an enolate, make support applications that require catalytic response.
A new type of catalyst, based on carbon, can facilitate two opposite reactions: electrolysis of water and combustion of hydrogen with oxygen. This bi-functionality, developed by researchers in Germany, is made possible from its construction: manganese-oxide or cobalt-oxide nanoparticles which are embedded in specially modified carbon, then integrated with nitrogen atoms in specific positions.
Researchers at the Univ. of California, Riverside have used a quartz-rich material to fabricate a lithium-ion battery that outperforms the current industry standard by three times. This key material? Sand. Through a heating process with salt and magnesium, the scientists created a porous nano-silicon sponge that greatly increases active surface area.
With a chemical “trick”, scientists in Germany have succeeded in isolating a stable gold carbene complex. Experts have been proposing gold carbenes as essential short-lived intermediates in catalytic reactions, but they elude study because of their high reactivity. Chemist Prof. Dr. Bernd F. Straub and his team are the first to have created the basis for directly examining the otherwise unstable gold-carbon double bond.
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