Electrolysis is often used to produce hydrogen that can be used for a storable fuel. Modified solar cells with highly efficient architecture can use this method to obtain hydrogen from water with the help of catalysts. But these solar cells rapidly corrode in aqueous electrolytes. By embedding the catalysts in an electrically conducting polymer, researchers have prevented this corrosion while maintaining competitive efficiency.
Nanoscopic crystals of silicon assembled like skyscrapers on wafer-scale substrates are being intensely studied as a possible breakthrough in highly efficient battery technologies. A researcher at Northeastern University has been using computational to understand the atomic-scale interactions between the growth of nanowires and new development in this area of technology: alloyed metal droplets.
The research team of Ulsan National Institute of Science and Technology paved a new way to affordable fuel cells with efficient metal-free electrocatalysts using edge-halogenated graphene nanoplatelets. The research team, for the first time, reportedly synthesized a series of edge-selectively halogenated graphene nanoplatelets by ball-milling graphite flake in the presence of chlorine, bromine or iodine, respectively.
Catalysts can stop working when atoms on the surface of those materials start moving. At the Vienna University of Technology, this “dance” of the atoms has been observed and explained: A certain type of molecule initiates a clustering process, which causes the catalyst atoms, like palladium, to ball together and disappear from contact with the surrounding gas.
Silicon can accept ten times more lithium than the graphite used in the electrodes in lithium-ion batteries, but silicon also expands, shortening electrode life. Looking for an alternative to pure silicon, scientists in Germany have now synthesized a novel framework structure consisting of boron and silicon, which could serve as electrode material.
Los Alamos National Laboratory scientists have designed a new type of nanostructured-carbon-based catalyst that could pave the way for reliable, economical next-generation batteries and alkaline fuel cells, providing for practical use of wind- and solar-powered electricity, as well as enhanced hybrid electric vehicles.
Chemical engineering researchers Wei Fan, Paul Dauenhauer, and colleagues at the University of Massachusetts Amherst report that they’ve discovered a new chemical process to make p-xylene, an important ingredient of common plastics, at 90% yield from lignocellulosic biomass, the highest yield achieved to date.
Ripening fruit, vegetables, and flowers release ethylene, which works as a plant hormone. Ethylene accelerates ripening, so other unripened fruit also begins to ripen—fruit and vegetables quickly spoil and flowers wilt. researchers in Japan have now introduced a new catalytic system for the fast and complete degradation of ethylene. This could keep the air in warehouses ethylene-free, keeping perishable products fresh longer.
A team from Argonne National Laboratory has worked for years to develop a new type of solar cell known as organic photovoltaics (OPVs). Because of their potential to reduce costs for both fabrication and materials, OPVs could be much cheaper to manufacture than conventional solar cells and have a smaller environmental impact as well. However, they aren’t as efficient as conventional solar cells due to one limitation.
Methanol to formaldehyde: This reaction is the starting point for the synthesis of many everyday plastics. Using catalysts made of gold particles, however, formaldehyde could be produced without the environmentally hazardous waste generated in conventional methods. But just how a gold catalyst could work has only recently been discovered by researchers.
Researchers from the U.S. Department of Energy’s (DOE) SLAC National Accelerator Laboratory and Stanford University have designed a low-cost, long-life battery that could enable solar and wind energy to become major suppliers to the electrical grid. The developers believe their new membrane-free battery, based on lithium and sulfur, may be the best yet designed to regulate alternative energies.
In recently published online paper, researchers at Brookhaven National Laboratory describe details of a low-cost, stable, effective catalyst that could replace costly platinum in the production of hydrogen. The catalyst, made from renewable soybeans and abundant molybdenum metal, produces hydrogen in an environmentally friendly, cost-effective manner, potentially increasing the use of this clean energy source.
A unique atomic-scale engineering technique for turning low-efficiency photocatalytic “white” nanoparticles of titanium dioxide into high-efficiency “black” nanoparticles could be the key to clean energy technologies based on hydrogen. Samuel Mao leads the development of a technique for engineering disorder into the nanocrystalline structure of the semiconductor titanium dioxide.
Controlling the shapes of nanometer-sized catalytic and electrocatalytic particles made from noble metals such as platinum and palladium may be more complicated than previously thought. Using systematic experiments, researchers have investigated how surface diffusion—a process in which atoms move from one site to another on nanoscale surfaces—affects the final shape of the particles.
Another innovative feature has been added to the world’s first practical “artificial leaf,” making the device even more suitable for providing people in developing countries and remote areas with electricity, scientists reported at the American Chemical Society’s National Meeting & Exposition this week. It gives the leaf the ability to self-heal damage that occurs during production of energy.
Researchers in Switzerland have used X-ray tomography to screen lithium-ion battery electrodes and have reconstructed these microstructures in high resolution. The flow behavior of the lithium ions, they have found, can be described by what is known as tortuosity. To put it simply, the more twisted the path of the ions through the electrode, the more slowly the battery is charged or discharged.
Wouldn't it be convenient if you could reverse the rusting of your car by shining a bright light on it? It turns out that this concept works for undoing oxidation on copper nanoparticles, and it could lead to an environmentally friendly production process for an important industrial chemical, University of Michigan engineers have discovered.
According to recent research at Rice University, vanadium oxide and graphene may be a key new set of materials for improving lithium-ion storage. Ribbons created at Rice from these two materials are thousands of times thinner than a sheet of paper, yet have potential that far outweighs current materials for their ability to charge and discharge very quickly. Initial capacity remains at 90% or more after more than 1,000 cycles.
Taking their inspiration from Nature, scientists at the University of New South Wales have developed a new method for carrying out chemical reduction—an industrial process used to produce fuels and chemicals that are vital for modern society. Their catalyst-based approach has the big advantages that it uses cheap, replenishable reagents and it works well at room temperature and in air—so much so, it can even be carried out safely in a teacup.
The ultrafast, ultrabright X-ray pulses of the Linac Coherent Light Source (LCLS) have enabled unprecedented views of a catalyst in action, an important step in the effort to develop cleaner and more efficient energy sources. Scientists at the SLAC National Accelerator Laboratory used LCLS, together with computerized simulations, to reveal surprising details of a short-lived early state in a chemical reaction occurring at the surface of a catalyst sample.
Bringing the concept of an “artificial leaf” closer to reality, a team of researchers at Massachusetts Institute of Technology has published a detailed analysis of all the factors that could limit the efficiency of such a system. The new analysis lays out a roadmap for a research program to improve the efficiency of these systems, and could quickly lead to the production of a practical, inexpensive and commercially viable prototype.
A new analytical theory has been developed at Purdue University that shows how to design experiments to study ways of controlling dendrite growth on electrodes in lithium-ion batteries. Using this approach, the researchers have shown theoretically how to control or eliminate the formation of these dendrites, which cause lithium-ion batteries to fail. The advance could help improve safety and might enable the batteries to be charged within a matter of minutes instead of hours.
The Fischer-Tropsch process is used for producing fuels from synthesis gas, which in turn is made from natural gas, biomass, or coal. Large reserves of shale or natural gas now changing the world energy market have raised interest in this technology, but prior reactors have been too bulky. Inspired by patents from the 1960s audio cassette recording industry, University of Amsterdam chemists have recently developed a new Fischer-Tropsch catalyst that is significantly cheaper and more scalable.
Tiny particles of titanium dioxide are found as key ingredients in common products such as paint and toothpaste. When reduced to the nanoscale, these particle acquire catalytic ability. A team of chemists has recently developed a synthesis to produce these nanoparticles at room temperature in a polymer network. Their analysis has revealed the crystalline structure of the nanoparticles and is a major step forward in the development of polymeric nanoreactors.
To make fuel cells more economical, engineers want a fast and efficient iron-based molecule that splits hydrogen gas to make electricity. Researchers at Pacific Northwest National Laboratory have recently reported the development of such a catalyst. Made from a synthetic molecule, it is the first iron-based catalyst that converts hydrogen directly to electricity, and it might help make those fuel cells less expensive.