University of Oregon chemists have identified a catalyst that could dramatically reduce the amount of waste made in the production of methyl methacrylate, a monomer used in the large-scale manufacturing of lightweight, shatter-resistant alternatives to glass such as Plexiglas.
Hydrogen is a clean fuel, producing only water vapor when it burns. But generating hydrogen in large quantities and in a "green" fashion is not straightforward. Biological photosynthesis includes an efficient reaction step that splits water into hydrogen and oxygen with the help of catalysts that have been used as models for synthetic catalysts. Working at the Advanced Photon Source at Argonne National Laboratory, a team of scientists has determined the structure of one such catalyst, a complex cobalt oxide.
Researchers from two SLAC-Stanford University joint institutes recently joined forces to investigate a catalyst that promotes energy-releasing reactions in fuel cells. What they discovered, after using high-resolution X-ray spectrometry, is that two different platinum-rhodium nanostructures behaved in strikingly different ways. The finding indicated the importance of careful engineering in catalyst design.
A team of researchers at the U.S. Department of Energy's Ames Laboratory has answered a key question concerning the widely used Fenton reaction—important in wastewater treatment to destroy hazardous organic chemicals and decontaminate bacterial pathogens and in industrial chemical production.
An international team of researchers has discovered that the catalytic activity of nanoporous gold originates from high concentrations of surface defects present within its complex 3D structure. The research has the potential to assist in the development of more efficient and durable catalytic converters and fuel cells because nanoporous gold is a catalytic agent for oxidizing carbon monoxide.
Researchers from the University of Pennsylvania, along with collaborators from Italy and Spain, have created a material that catalyzes the burning of methane 30 times better than currently available catalysts. The discovery offers a way to more completely exploit energy from methane, potentially reducing emissions of this greenhouse gas from vehicles that run on natural gas.
Using a universal transfer approach, a team of engineers in Korea have built a flexible lithium-ion battery structured with high density inorganic thin films. The innovation has potential as an essential energy source for flexible displays.
Washington University in St. Louis recently landed a $2 million U.S. Dept. of Energy grant with $1.2 million in matching funds from the university to design a battery management system for lithium-ion batteries that will guarantee their longevity, safety and performance. The development is geared toward electric vehicle technologies.
A research team has built an air-breathing battery that uses the chemical energy generated by the oxidation of iron plates that are exposed to the oxygen in the air—a process similar to rusting. The concept has been around for decades, but competing chemical reaction of hydrogen generation sucked away about 50% of the battery’s energy. Recent breakthroughs have lowered this loss to just 4%.
Scientists at Lawrence Berkeley National Laboratory have developed a catalyst and deployment devices to improve indoor air quality and reduce ventilation energy needs.
Ultracapacitors can be recharged hundreds of thousands of times without degrading, but its voltage output drops precipitously as the device is discharged. A new type of capacitor has been designed by a University of West Florida researcher that maintains a near steady voltage as it is discharged. The key is the level of exposure it has to the electrolyte solution.
Scientists who have recently calculated microscopic reaction mechanisms in the promising energy storage material aluminum hydride are challenging outdated reaction curve interpretations. Their findings show how the creation of vacancies in hydrogen enables the release rate of the gas to be fast, but not too fast.
According to a Case Western Reserve University researcher, fuel cells are inefficient because the catalyst most commonly used to convert chemical energy to electricity is made of the wrong material. Platinum, he says, is like putting a resistor in the system. He also says existing explanations as to why platinum is the wrong material don’t do enough to explain its drawbacks.
A team of researchers from Drexel University has pioneered a new method for quickly and efficiently storing large amounts of electrical energy. Their solution is an electrochemical flow capacitor, which combines the strengths of batteries and supercapacitors while also negating the scalability problem.
California Institute of Technology chemists have developed a new class of catalysts that will increase the range of chemicals that can be synthesized using environmentally friendly methods. The new chemicals include the metal ruthenium and help drive a chemical reaction called olefin metathesis. The reaction has proven useful and efficient for making chemical products that involve pairs of carbon atoms connected by double bonds.
Imagine a kerosene lamp that continued to shine after the fuel was spent. Materials scientists at Harvard University have demonstrated an equivalent feat in clean energy generation with a solid-oxide fuel cell that converts hydrogen into electricity but can also store electrochemical energy like a battery. This fuel cell can continue to produce power for a short time after its fuel has run out.
In the first side-by-side tests of a half-dozen palladium- and iron-based catalysts for cleaning up the carcinogen TCE, Rice University scientists have found that palladium destroys TCE far faster than iron—up to a billion times faster in some cases.
Engineers at the University of Wisconsin-Milwaukee have identified a catalyst that provides the same level of efficiency in microbial fuel cells as the currently used platinum catalyst, but at 5% of the cost. Since more than 60% of the investment in making microbial fuel cells is the cost of platinum, the discovery may lead to much more affordable energy conversion and storage devices.
Chemists don't like precious metals—at least not when they need to expensive materials as catalysts to accelerate reactions or guide them in a particular direction. And this is often the case. However, a team of scientists has now developed a catalyst using iron and aluminum that works just as well as the conventional palladium catalyst, but costs much less.
The design of a nature-inspired material that can make energy-storing hydrogen gas has gone holistic. Usually, tweaking the design of this particular catalyst—a work in progress for cheaper, better fuel cells—results in either faster or more energy-efficient production but not both. Now, researchers have found a condition that creates hydrogen faster without a loss in efficiency.
In a search for an inexpensive alternative to platinum, a team including researchers from Oak Ridge National Laboratory turned to carbon to develop a multi-walled carbon nanotube complex that consists of cylindrical sheets of carbon. The complex featured the desired properties, but researchers didn’t know why until they tried an innovative mix of electron imaging and spectroscopy to understand the relationships at play.
Eons ago, nature solved the problem of converting solar energy to fuels by inventing the process of photosynthesis. Plants convert sunlight to chemical energy in the form of biomass, while releasing oxygen as an environmentally benign byproduct. Devising a similar process by which solar energy could be captured and stored for use in vehicles or at night is a major focus of modern solar energy research.
Scientists from SLAC National Accelerator Laboratory, Stanford University, and Germany have figured out a key part of the industrial process for making methanol. It’s an important step toward improving the process—and eventually realizing the goal of turning a potent greenhouse gas, carbon dioxide, into fuel.
An international team of researchers has discovered how adding trace amounts of water can tremendously speed up chemical reactions—such as hydrogenation and hydrogenolysis—in which hydrogen is one of the reactants, or starting materials. Previous research had indicated this phenomenon, but until now the true importance of water to its effect has eluded chemists.
A detailed description of development of the first practical device that mimics the process of photosynthesis has recently been published in an American Chemical Society journal. Unlike earlier devices, which used costly ingredients, the new device is made from inexpensive materials and employs low-cost engineering and manufacturing processes.