Materials in lithium ion battery electrodes expand and contract during charge and discharge. These volume changes drive particle fracture, which shortens battery lifetime. A group of scientists has quantified this effect for the first time using high-resolution 3D movies recorded using x-ray tomography at the Swiss Light Source.
Dow Chemical Co. is selling its global polypropylene licensing and catalysts business to W.R. Grace & Co. for $500 million. The sale includes Dow Chemical's polypropylene catalysts manufacturing plant in Norco, La., and customer contracts, licenses, intellectual property and inventory.
Researchers report that they have created a man-made catalyst that is an “enzyme mimic.” Unlike most enzymes, which act on a single target, the new catalyst can alter the chemical profiles of numerous types of small molecules. The catalyst—and others like it—will greatly speed the process of drug discovery, the researchers say.
By coating compact disks in photocatalytic compounds and spinning them to clean water, scientists in Taiwan have found a potential new use for old music CDs. The disks, equipped with tiny zinc oxide nanorods, are able to break down more than 95% of the contaminants in methyl orange dye, a benchmark organic compound for testing photocatalytic reactions.
Magnesium is a lightweight metal used in cars and planes to improve their fuel efficiency. But it currently requires a lot of energy and money to produce the metal. Engineers at Pacific Northwest National Laboratory is developing a new production method that would be 50% more energy efficient than the United States' current production process.
A lightweight metal that reduces fuel use in cars and planes could be extracted from the ocean through a unique process being developed at the Pacific Northwest National Laboratory. The process could ultimately make fuel-efficient transportation more affordable and expand the American magnesium market.
Carbon monoxide is a poisoning impurity in hydrogen derived from natural gas. If a catalyst could be developed that can handle this impure fuel, it could be a substantially less expensive alternative to pure hydrogen produced from water. Scientists at Brookhaven National Laboratory have used a simple, “green” process to create a new core-shell catalyst that tolerates carbon monoxide in fuel cells.
Researchers have found a new family of materials that provides the best-ever performance in a reaction called oxygen evolution, a key requirement for energy storage and delivery systems. The materials, called double perovskites, are a variant of a mineral that exists in abundance in the Earth’s crust. Their remarkable ability to promote oxygen evolution in a water-splitting reaction is detailed in a paper appearing in Nature Communications.
Chemists' efforts to study the inner workings of dirhodium metal complex reactions have been hindered by their extreme efficiency and speed, reacting at about 300 times per second. Now, a team of scientists report an advance that freezes one step of the process, rhodium catalysis, long enough to offer researchers a glimpse into the finer mechanism.
Researchers report the development of a supercapacitor that is reliable at temperatures of up to 200 C and possibly beyond. Potentially useful for powering devices for use in extreme environments, such as oil drilling, the military and space, the supercapacitor is made possible by the key ingredient, clay, which forms the basis of a new electrolyte.
Bionic leaves that could produce fuels from nothing more than sunlight, water and carbon dioxide, with no byproducts other than oxygen, represent an ideal alternative to fossil fuels but also pose numerous scientific challenges. In a major advance, researchers at Lawrence Berkeley National Laboratory have developed a method by which molecular hydrogen-producing catalysts can be interfaced with a semiconductor that absorbs visible light.
Polyethylene, an inexpensive commodity plastic, has been successfully used by researchers to synthesize the “ideal” polymer nanocrystal. Normally, this plastic is only partly crystalline, but a new catalyst has produced material that eliminates amorphous structures. The crystalline nanostructure could prove of interest to production of new kinds of coatings.
Chemists have unexpectedly made two differently colored crystals—one orange, the other blue—from one chemical in the same flask while studying a special kind of molecular connection called an agostic bond. The discovery is providing new insights into important industrial chemical reactions such as those that occur while making plastics and fuels.
Taking inspiration from trees, scientists have developed a battery made from a sliver of wood coated with tin that shows promise for becoming a tiny, long-lasting, efficient and environmentally friendly energy source. The device, developed at the Univ. of Maryland, is 1,000 times thinner than a sheet of paper.
Fixation processes free up nitrogen atoms from their diatomic form, but nitrogen does not easily react with other chemicals to form new compounds. Researchers in South Korea have invented a simple and eco-friendly method of creating nitrogen-doped graphene nanoplatelets that simultaneously facilitates the nitrogen-fixation process and creates useful tools for building dye-sensitized solar cells and fuel cells.
Catalysts are everywhere. They make chemical reactions that normally occur at extremely high temperatures and pressures possible within factories, cars and the comparatively balmy conditions within the human body. Developing better catalysts, however, is mainly a hit-or-miss process. Now, researchers have shown a way to precisely design the active elements of a certain class of catalysts.
Catalysts are everywhere, but developing better catalysts is mainly a hit-or-miss process. Now, a study by researchers at the University of Pennsylvania, the University of Trieste, Italy, and Brookhaven National Laboratory has shown a way to precisely design the active elements of a certain class of catalysts, showing which parameters are most critical for improving performance.
The Air Force Office of Scientific Research has been working with Jim Tour’s laboratory at Rice University to make graphene suitable for a variety of organic chemistry applications. Recently, the partnership made another technological advance. Their work has shown that graphene nanoribbons can significantly increase the storage capacity of lithium ion by combining these 2D ribbons with tin oxide.
The research team from the Ulsan National Institute of Science and Technology in South Korea has developed an inexpensive and scalable bio-inspired composite electrocatalyst, designed using iron phthalocyanine, a macrocyclic compound, anchored to single-walled carbon nanotubes. Under certain conditions, the new catalyst has a higher electrocatalytic activity than platinum-based catalysts, and better durability during cycling.
There are a lot of small molecules people would like to convert to something useful. The current process for reducing nitrogen to ammonia is done under extreme conditions, and there is an enormous barrier to overcome to get a final product. Breaching that barrier more efficiently and reducing the huge amounts of energy used to convert nitrogen to ammonia has been a grail for the agricultural chemical industry, until now.
Hydrogenation is a chemical process used in a wide range of industrial applications, from food products to petrochemicals and pharmaceuticals. The process typically involves the use of heavy metals, such as palladium or platinum, which, though efficient, are expensive and can be toxic. However, researchers have discovered way to use iron as a catalyst for hydrogenation.
Waste from textile and paint industries often contains organic dyes such as methylene blue as pollutants. Photocatalysis is an efficient means of reducing such pollution, and molybdenum trioxide catalyzes this degradation. Researchers in India now report four methods to produce nanosheets made of very few layers of molybdenum trioxide, which are more efficient than their bulk counterparts.
Electrolysis is often used to produce hydrogen that can be used for a storable fuel. Modified solar cells with highly efficient architecture can use this method to obtain hydrogen from water with the help of catalysts. But these solar cells rapidly corrode in aqueous electrolytes. By embedding the catalysts in an electrically conducting polymer, researchers have prevented this corrosion while maintaining competitive efficiency.
Nanoscopic crystals of silicon assembled like skyscrapers on wafer-scale substrates are being intensely studied as a possible breakthrough in highly efficient battery technologies. A researcher at Northeastern University has been using computational to understand the atomic-scale interactions between the growth of nanowires and new development in this area of technology: alloyed metal droplets.
The research team of Ulsan National Institute of Science and Technology paved a new way to affordable fuel cells with efficient metal-free electrocatalysts using edge-halogenated graphene nanoplatelets. The research team, for the first time, reportedly synthesized a series of edge-selectively halogenated graphene nanoplatelets by ball-milling graphite flake in the presence of chlorine, bromine or iodine, respectively.