Atomic-scale snapshots of a bimetallic nanoparticle catalyst in action have provided insights that could help improve the industrial process by which fuels and chemicals are synthesized from natural gas, coal or plant biomass. A multinational laboratory collaboration has taken the most detailed look ever at the evolution of platinum/cobalt bimetallic nanoparticles during reactions in oxygen and hydrogen gases.
Surface catalysts are notoriously difficult to study mechanistically, but scientists at two universities have recently shown how to get real-time reaction information from silver nanocatalysts that have long frustrated attempts to describe their kinetic behavior in detail. The key to the team's success was bridging a size gap that had represented a wide chasm to researchers in the past.
Wouldn’t it be nice to use solar- or wind-generated electricity to turn excess carbon dioxide into fuels and other useful chemicals? The process would store up the intermittent solar or wind energy in a form that could be used when and where it was needed, including in transportation applications, all while getting rid of some greenhouse gas.
When crude oil is refined to fuels and chemicals, catalysts such as zeolites. are at work making this process happen. Scientists have recently developed a reference parameter for the performance of this important class of catalysts, which can suffer from production hindrances if reaction side products clog pores or block active sites on the catalyst.
Researchers in Japan have developed a new nickel catalyst with a “kabuto-like” structure that was found to catalyze the cross-coupling reaction between carbonyl compounds and readily available phenol derivatives, to form arylketones, which are found in many biologically active compounds. A kabuto is a helmet worn by Japanese samurai.
Soon after graphene’s isolation, early research already showed that lithium batteries with graphene in their electrodes had a greater capacity and lifespan than standard designs. At the Univ. of Manchester, U.K., where graphene was first isolated, researchers are working with more than 30 companies to advance technology in graphene-enabled energy storage, particularly in the area of lithium-ion batteries and supercapacitors.
This gift from science just keeps on giving. Measurements taken at NIST show why a material already known to be good at separating components of natural gas also can do something trickier: help convert one chemical to another, a process called catalysis. The discovery is a rare example of a laboratory-made material easily performing a task that biology usually requires a complex series of steps to accomplish.
Photocatalysis is a promising route to convert solar energy into chemical fuels, or to split water into molecular hydrogen. But viable photocatalysts, or promoters, for these applications are scarce. A team of chemists in California has come up with a model to explain this promoting effect that could shift the focus in the search for substitutes of the metals, and help identify better promoters for photocatalysis in the near future.
A poet and a scientist at the Univ. of Sheffield in the U.K. have collaborated to create a catalytic poem called “In Praise of Air”. The poem is printed on material containing a formula invented at the university which is capable of removing nitrogen oxide from the atmosphere. According to its developers, the cheap technology could also be applied to billboards and advertisements alongside congested roads to cut pollution.
As news reports of lithium-ion battery (LIB) fires in Boeing Dreamliner planes and Tesla electric cars remind us, these batteries, which are in everyday portable devices, like tablets and smartphones, have their downsides. Now, scientists have designed a safer kind of lithium battery component that is far less likely to catch fire and still promises effective performance.
The chemistry of lithium-ion batteries limits how much energy they can store, and one promising solution is the lithium-sulfur battery, which can hold as much as four times more energy per mass. However, problematic polysulfides usually cause lithium-sulfur batteries to fail after a few charges. Researchers at Pacific Northwest National Laboratory, however, have developed a new powdery nanomaterial that could solve the issue.
Stanford Univ. scientists have found a new, highly efficient way to produce liquid ethanol from carbon monoxide gas. This promising discovery could provide an eco-friendly alternative to conventional ethanol production from corn and other crops, say the scientists. Their results are published online in Nature.
Recent experiments in Austria have explained the behavior of electrons at tiny step edges on titanium oxide surfaces. The finding, which shows why oxygen atoms attach so well to these edges, is important for solar cell technology and novel, more effective catalysts.
Navy researchers have recently demonstrated sustained flight of a radio-controlled P-51 fighter replica fueled by a new gas-to-liquid process that uses seawater as carbon feedstock. The fuel is made using an innovative and proprietary electrolytic cation exchange module that separates gases from water at 92% efficiency. Catalysis converts the gases to liquid hydrocarbons.
Biomass is a good alternative for fossil fuels, but converting biomass into useful chemicals and fuels is difficult in practice. The metal oxide CeO2 can help the process by activating water, but until recent research in the Netherlands, it was not clear in which form the reactivity of this catalyst was highest.
Lithium-ion batteries power a vast array of modern devices, from cell phones, laptops, and laser pointers to thermometers, hearing aids, and pacemakers. The electrodes in these batteries typically comprise three components: active materials, conductive additives, and binders. Now, a team of researchers at the Univ. of Delaware has discovered a “sticky” conductive material that may eliminate the need for binders.
Phosphorus can be found in fertilizers, drinks and detergents, and it accumulates in waterways, polluting them. For this reason, researchers in Germany have developed a new platform for recovering this valuable but harmful element from water. They have attached bonding sites for phosphorus to particles so that they fish the phosphate anions out of the water and carry them “piggyback”. The particles can be applied using a magnet.
A new study by Berkeley Lab researchers shows that nearly 90% of the electrons generated by a hybrid material designed to store solar energy in hydrogen are being stored in the target hydrogen molecules. Interfacing the semiconductor gallium phosphide with a cobaloxime catalyst provides an inexpensive photocathode for bionic leaves that produce energy-dense fuels from nothing more than sunlight, water and carbon dioxide.
Massachusetts Institute of Technology chemists have devised a way to trap carbon dioxide and transform it into useful organic compounds, using a simple metal complex. More work is needed to understand and optimize the reaction, but one day this approach could offer an easy and inexpensive way to recapture some of the carbon dioxide emitted by vehicles and power plants.
A key to realizing commercial-scale artificial photosynthesis technology is the development of electrocatalysts that can efficiently and economically carry out water oxidation reaction that is critical to the process. Heinz Frei, a chemist Lawrence Berkeley National Laboratory, has been at the forefront of this research effort. His latest results represent an important step forward.
A big step in the development of advanced fuel cells and water-alkali electrolyzers has been achieved with the discovery of a new class of bimetallic nanocatalysts that are an order of magnitude higher in activity than the target set by the U.S. Department of Energy for 2017. The new catalysts feature a 3-D catalytic surface activity that makes them significantly more efficient and far less expensive than the best platinum catalysts.
A pathway to more effective and efficient synthesis of pharmaceutical drugs and other flow reactor chemical products has been opened by a study in which, for the first time, the catalytic reactivity inside a microreactor was mapped in high resolution from start-to-finish. The results not only provided a better understanding of the chemistry behind the catalytic reactions, they also revealed opportunities for optimization.
The scarcity of ultraviolet (UV) light in sunlight has held back the usefulness of titanium dioxide-based photocatalysts. Through the application of nanotechnology, researchers in Japan have recently succeeded in the development of better titanium dioxide-based material that can be activated by visible light. The solution lies in an array of nanoparticles that “simulate” the photoexcitation of UV light.
A team of researchers at the Univ. of Delaware has developed a highly selective catalyst capable of electrochemically converting carbon dioxide to carbon monoxide with 92% efficiency. The carbon monoxide then can be used to develop useful chemicals. The exceptionally high activity of the new electrocatalyst is due to its extremely large and highly curved internal surface.
Researchers from two continents have engineered an efficient and environmentally friendly catalyst for the production of molecular hydrogen (H2), a compound used extensively in modern industry to manufacture fertilizer and refine crude oil into gasoline. The new method can product industrial quantities of hydrogen without emitting carbon into the atmosphere.