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The Lead

Chemists develop technology to produce clean-burning hydrogen fuel

July 14, 2014 9:12 am | News | Comments

Rutgers Univ. researchers have developed a technology that could overcome a major cost barrier to make clean-burning hydrogen fuel. The new catalyst is based on carbon nanotubes and may rival cost-prohibitive platinum for reactions that split water into hydrogen and oxygen.

Oxygen extends graphene’s reach

July 11, 2014 1:05 pm | News | Comments

The addition of elements to the surface of...

Chemists develop novel catalyst with two functions

July 9, 2014 8:47 am | by Dr. Julia Weiler, Ruhr Univ. Bochum | News | Comments

A new type of catalyst, based on carbon, can...

Using sand to improve battery performance

July 8, 2014 7:43 pm | by Sean Nealon, Univ. of California, Riverside | News | Comments

Researchers at the Univ. of California, Riverside...

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Highly reactive gold carbene complex shines in emerald green

July 8, 2014 1:09 pm | News | Comments

With a chemical “trick”, scientists in Germany have succeeded in isolating a stable gold carbene complex. Experts have been proposing gold carbenes as essential short-lived intermediates in catalytic reactions, but they elude study because of their high reactivity. Chemist Prof. Dr. Bernd F. Straub and his team are the first to have created the basis for directly examining the otherwise unstable gold-carbon double bond.

Water-cleanup catalysts tackle biomass upgrading

June 26, 2014 12:33 pm | by Mike Williams, Rice Univ. | News | Comments

Rice Univ. chemical engineer Michael Wong has spent a decade amassing evidence that palladium-gold nanoparticles are excellent catalysts for cleaning polluted water, but even he was surprised at how well the particles converted biodiesel waste into valuable chemicals.

A new solution for storing hydrogen fuel

June 11, 2014 8:36 am | News | Comments

Turning the “hydrogen economy” concept into a reality, even on a small scale, has been a bumpy road, but scientists are developing a novel way to store hydrogen to smooth out the long-awaited transition away from fossil fuels. Their report on a new solid, stable material that can pack in a large amount of hydrogen that can be used as a fuel appears in Chemistry of Materials.

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Charging portable electronics in 10 minutes

June 10, 2014 3:09 pm | by Sean Nealon, UC Riverside | News | Comments

Researchers at the University of California, Riverside Bourns College of Engineering have developed a 3-D, silicon-decorated, cone-shaped carbon-nanotube cluster architecture for lithium ion battery anodes that could enable charging of portable electronics in 10 minutes. It also increases cell capacity and reduces size and weight by 40%.

Designing ion “highway systems” for batteries

June 10, 2014 2:19 pm | News | Comments

Since the early 1970s, lithium has been the most popular element for batteries because of it’s low weight and good electrochemical potential. But it is also highly flammable. Researchers have recently married two traditional theories in materials science that can explain how the charge dictates the structure of the material. And using this they may be able to move to other materials, such as block copolymers, for use in batteries.

Evolution of a bimetallic nanocatalyst

June 9, 2014 7:58 am | by Lynn Yarris, Lawrence Berkeley National Laboratory | News | Comments

Atomic-scale snapshots of a bimetallic nanoparticle catalyst in action have provided insights that could help improve the industrial process by which fuels and chemicals are synthesized from natural gas, coal or plant biomass. A multinational laboratory collaboration has taken the most detailed look ever at the evolution of platinum/cobalt bimetallic nanoparticles during reactions in oxygen and hydrogen gases.

Opening a wide window on the nano-world of surface catalysis

June 6, 2014 10:20 am | by Steven Powell, Univ. of South Carolina | News | Comments

Surface catalysts are notoriously difficult to study mechanistically, but scientists at two universities have recently shown how to get real-time reaction information from silver nanocatalysts that have long frustrated attempts to describe their kinetic behavior in detail. The key to the team's success was bridging a size gap that had represented a wide chasm to researchers in the past.

Ionic liquid boosts efficiency of carbon dioxide reduction catalyst

June 6, 2014 7:50 am | by Karen McNulty Walsh, Brookhaven National Laboratory | News | Comments

Wouldn’t it be nice to use solar- or wind-generated electricity to turn excess carbon dioxide into fuels and other useful chemicals? The process would store up the intermittent solar or wind energy in a form that could be used when and where it was needed, including in transportation applications, all while getting rid of some greenhouse gas.

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New reference to enable better petrochemical catalysts

May 29, 2014 11:51 am | by Fabio Bergamin, ETH Zurich | News | Comments

When crude oil is refined to fuels and chemicals, catalysts such as zeolites. are at work making this process happen. Scientists have recently developed a reference parameter for the performance of this important class of catalysts, which can suffer from production hindrances if reaction side products clog pores or block active sites on the catalyst.

New nickel catalyst forms bioactive frameworks from low-cost phenol derivatives

May 27, 2014 12:23 pm | News | Comments

Researchers in Japan have developed a new nickel catalyst with a “kabuto-like” structure that was found to catalyze the cross-coupling reaction between carbonyl compounds and readily available phenol derivatives, to form arylketones, which are found in many biologically active compounds. A kabuto is a helmet worn by Japanese samurai.

Graphene may make large scale electricity storage a reality

May 27, 2014 9:35 am | News | Comments

Soon after graphene’s isolation, early research already showed that lithium batteries with graphene in their electrodes had a greater capacity and lifespan than standard designs. At the Univ. of Manchester, U.K., where graphene was first isolated, researchers are working with more than 30 companies to advance technology in graphene-enabled energy storage, particularly in the area of lithium-ion batteries and supercapacitors.

Metal-organic framework shows new talent

May 21, 2014 8:15 am | News | Comments

This gift from science just keeps on giving. Measurements taken at NIST show why a material already known to be good at separating components of natural gas also can do something trickier: help convert one chemical to another, a process called catalysis. The discovery is a rare example of a laboratory-made material easily performing a task that biology usually requires a complex series of steps to accomplish.

Chemists challenge conventional understanding of photocatalysis

May 21, 2014 8:13 am | by Iqbal Pittalwala, UC Riverside | News | Comments

Photocatalysis is a promising route to convert solar energy into chemical fuels, or to split water into molecular hydrogen. But viable photocatalysts, or promoters, for these applications are scarce. A team of chemists in California has come up with a model to explain this promoting effect that could shift the focus in the search for substitutes of the metals, and help identify better promoters for photocatalysis in the near future.

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Writing is on the wall for air pollution thanks to air-cleansing poem

May 15, 2014 12:23 pm | News | Comments

A poet and a scientist at the Univ. of Sheffield in the U.K. have collaborated to create a catalytic poem called “In Praise of Air”. The poem is printed on material containing a formula invented at the university which is capable of removing nitrogen oxide from the atmosphere. According to its developers, the cheap technology could also be applied to billboards and advertisements alongside congested roads to cut pollution.

In the wake of high-profile battery fires, a safer approach emerges

May 14, 2014 9:36 am | News | Comments

As news reports of lithium-ion battery (LIB) fires in Boeing Dreamliner planes and Tesla electric cars remind us, these batteries, which are in everyday portable devices, like tablets and smartphones, have their downsides. Now, scientists have designed a safer kind of lithium battery component that is far less likely to catch fire and still promises effective performance.

Relieving electric vehicle range anxiety with improved batteries

April 15, 2014 3:29 pm | News | Comments

The chemistry of lithium-ion batteries limits how much energy they can store, and one promising solution is the lithium-sulfur battery, which can hold as much as four times more energy per mass. However, problematic polysulfides usually cause lithium-sulfur batteries to fail after a few charges. Researchers at Pacific Northwest National Laboratory, however, have developed a new powdery nanomaterial that could solve the issue.

Scientists discover way to make ethanol without corn, other plants

April 10, 2014 9:00 am | by Mark Shwartz, Stanford Univ. | News | Comments

Stanford Univ. scientists have found a new, highly efficient way to produce liquid ethanol from carbon monoxide gas. This promising discovery could provide an eco-friendly alternative to conventional ethanol production from corn and other crops, say the scientists. Their results are published online in Nature.

Tiny “step edges” are a big step for surface science

April 9, 2014 2:59 pm | News | Comments

Recent experiments in Austria have explained the behavior of electrons at tiny step edges on titanium oxide surfaces. The finding, which shows why oxygen atoms attach so well to these edges, is important for solar cell technology and novel, more effective catalysts.

Scale model World War II craft takes flight with fuel from the sea

April 7, 2014 6:06 pm | News | Comments

Navy researchers have recently demonstrated sustained flight of a radio-controlled P-51 fighter replica fueled by a new gas-to-liquid process that uses seawater as carbon feedstock. The fuel is made using an innovative and proprietary electrolytic cation exchange module that separates gases from water at 92% efficiency. Catalysis converts the gases to liquid hydrocarbons.

Shape helps catalyst extract energy from biomass

April 2, 2014 6:06 am | News | Comments

Biomass is a good alternative for fossil fuels, but converting biomass into useful chemicals and fuels is difficult in practice. The metal oxide CeO2 can help the process by activating water, but until recent research in the Netherlands, it was not clear in which form the reactivity of this catalyst was highest.

New battery technology employs sticky composites

March 26, 2014 9:20 am | by Diane Kukich, Univ. of Delaware | News | Comments

Lithium-ion batteries power a vast array of modern devices, from cell phones, laptops, and laser pointers to thermometers, hearing aids, and pacemakers. The electrodes in these batteries typically comprise three components: active materials, conductive additives, and binders. Now, a team of researchers at the Univ. of Delaware has discovered a “sticky” conductive material that may eliminate the need for binders.

Recovering valuable substances from wastewater

March 24, 2014 9:54 am | News | Comments

Phosphorus can be found in fertilizers, drinks and detergents, and it accumulates in waterways, polluting them. For this reason, researchers in Germany have developed a new platform for recovering this valuable but harmful element from water. They have attached bonding sites for phosphorus to particles so that they fish the phosphate anions out of the water and carry them “piggyback”. The particles can be applied using a magnet.

New hybrid material promising for solar fuels

March 9, 2014 11:42 pm | by Lynn Yarris, Lawrence Berkeley National Laboratory | News | Comments

A new study by Berkeley Lab researchers shows that nearly 90% of the electrons generated by a hybrid material designed to store solar energy in hydrogen are being stored in the target hydrogen molecules. Interfacing the semiconductor gallium phosphide with a cobaloxime catalyst provides an inexpensive photocathode for bionic leaves that produce energy-dense fuels from nothing more than sunlight, water and carbon dioxide.

New catalyst could lead to cleaner energy

March 6, 2014 8:20 am | by Anne Trafton, MIT News Office | News | Comments

Massachusetts Institute of Technology chemists have devised a way to trap carbon dioxide and transform it into useful organic compounds, using a simple metal complex. More work is needed to understand and optimize the reaction, but one day this approach could offer an easy and inexpensive way to recapture some of the carbon dioxide emitted by vehicles and power plants.

Researchers identify key intermediate steps in artificial photosynthesis reaction

March 3, 2014 2:42 pm | by Lyn Yarris, Berkeley Lab | News | Comments

A key to realizing commercial-scale artificial photosynthesis technology is the development of electrocatalysts that can efficiently and economically carry out water oxidation reaction that is critical to the process. Heinz Frei, a chemist Lawrence Berkeley National Laboratory, has been at the forefront of this research effort. His latest results represent an important step forward.

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