Techniques for self-assembling of molecules have grown increasingly sophisticated, but biological structures remain a challenge. Recently, scientists have used self-assembly under controlled conditions to create a membrane consisting of layers with distinctly different structures. At the Advanced Photon Source, the team has studied the structures and how they form, paving the way for hierarchical structures with biomedical applications.
Researchers at McGill Univ. have succeeded in simultaneously observing the reorganizations of atomic positions and electron distribution during the transformation of the “smart material” vanadium dioxide from a semiconductor into a metal. The observations are made in a time frame a trillion times faster than the blink of an eye.
Tiny, soapy bubbles can reorganize their membranes to let material flow in and out in response to the surrounding environment, according to new research. This behavior could be exploited in creating microbubbles that deliver drugs or other payloads inside the body, and could help us understand how the very first living cells on Earth might have survived billions of years ago.
A research team led by a Brown Univ. physicist has produced new evidence for an exotic superconducting state, first predicted a half-century ago, that can arise when a superconductor is exposed to a strong magnetic field. This new understanding of what happens when electron spin populations become unequal could have implications beyond superconductivity.
The trend toward energy self-sufficient probes and ever smaller mobile electronics systems continues, and are used to monitor the status of the engines on airplanes, or for medical implants. They gather the energy they need for this from their immediate environment, such as vibrations. Fraunhofer Institute researchers have developed a process for the economical production of piezoelectric materials that supply this type of energy.
Researchers at Virginia Commonwealth Univ. have discovered that most of the electrolytes used in lithium-ion batteries are superhalogens, and that the vast majority of these electrolytes contain toxic halogens. At the same time, the researchers also found that the electrolytes in lithium-ion batteries could be replaced with halogen-free electrolytes that are both nontoxic and environmentally friendly.
Researchers in the U.K. have found a new way to make nanostructured carbon using the waste product sawdust. By cooking sawdust with a thin coating of iron at 700 C, they have discovered that they can create carbon with a structure made up of many tiny tubes. These tubes are one thousand times smaller than an average human hair.
Scientists have been able to manufacture 3-D isotropic metamaterials, but up to now only on a very small scale. Now, in a significant breakthrough, scientists from RIKEN, in collaboration with colleagues in Taiwan, have succeeded in creating a large metamaterial up to 4-mm-square in size that is essentially isotropic, using a type of metamaterial element called a split-ring resonator.
When a solid material is immersed in a liquid, the liquid immediately next to its surface differs from that of the bulk liquid at the molecular level. This interfacial layer is critical to our understanding of a diverse set of phenomena. When the solid surface is charged, it can drive further changes in the interfacial liquid. However, elucidating the molecular structure at the solid-liquid interface under these conditions is difficult.
An international team of scientists have become the first to successfully reach temperatures below -272.15 C, which is just above absolute zero, using magnetic molecules. The effort, which avoids the use of helium, depends on a form of gadolinium that appropriately has a structure resembling a snowflake.
A few short years ago, the idea of a practical manufacturing process based on getting molecules to organize themselves in useful nanoscale shapes seemed far-fetched. Recent work at NIST, Massachusetts Institute of Technology and IBM Almaden Research Center suggest this capability isn’t far off, however, by demonstrating self-assembly of thin films on a polymer template that creates precise rows just 10 nm wide.
Nature has developed a wide variety of methods for guiding particular cells, enzymes and molecules to specific structures inside the body: White blood cells can find their way to the site of an infection, while scar-forming cells migrate to the site of a wound. But finding ways of guiding artificial materials within the body has proven more difficult.
Univ. of Oregon chemists have devised a way to see the internal structures of electronic waves trapped in carbon nanotubes by external electrostatic charges. Their atomic scale observations provide a detailed view of traps that disrupt energy flow, possibly pointing toward improved charge-carrying devices.
Scientists at Ames Laboratory have developed deeper understanding of the ideal design for mesoporous nanoparticles used in catalytic reactions, such as hydrocarbon conversion to biofuels. The research will help determine the optimal diameter of channels within the nanoparticles to maximize catalytic output.
Researchers in Australia have discovered that nano-sized fragments of graphene have the ability to speed up the rate of chemical reactions. The finding is significant, say researchers, because it suggested that graphene might have potential applications in catalyzing chemical reactions of industrial importance.
Scientists at Oak Ridge National Laboratory have discovered exceptional properties in a garnet material that could enable development of higher-energy battery designs. The team used electron microscopy to take an atomic-level look at a cubic garnet material called LLZO. The researchers found the material to be highly stable in a range of aqueous environments, making the compound a promising component in new battery configurations.
Research by an international team of scientists has uncovered a new, unpredicted behavior in a copper oxide material that becomes superconducting at relatively high temperatures. This new phenomenon presents a challenge to scientists seeking to understand its origin and connection with high-temperature superconductivity. Their ultimate goal is to design a superconducting material that works at room temperature.
Several types of plastic pipes in eco-friendly green buildings in the U.S. have been found to leach chemicals into drinking water that can cause odors and sometimes exist at levels that may exceed health standards. Purdue Univ. engineering professor Andrew Whelton will detail these findings during the 2014 U.S. Green Building Council’s Greenbuild International Conference & Exposition on Oct. 24 in New Orleans.
Research at Oak Ridge National Laboratory has cracked one mystery of glass to shed light on the mechanism that triggers its deformation before shattering. The study improves understanding of glassy deformation and may accelerate broader application of metallic glass, a moldable, wear-resistant, magnetically exploitable material that is thrice as strong as the mightiest steel and ten times as springy.
Microscopic particles that bind under low temperatures will melt as temperatures rise to moderate levels, but re-connect under hotter conditions, a team of New York Univ. scientists has found. Their discovery points to new ways to create "smart materials," cutting-edge materials that adapt to their environment by taking new forms, and to sharpen the detail of 3-D printing.
Personal electronics such as cell phones and laptops could get a boost from some of the lightest materials in the world. Lawrence Livermore National Laboratory researchers have turned to graphene aerogel for enhanced electrical energy storage that eventually could be used to smooth out power fluctuations in the energy grid.
Washington State Univ. (WSU) researchers have developed a new catalyst that could lead to making biofuels cheaply and more efficiently. The WSU researchers developed a mixture of two metals, iron along with a tiny amount of palladium, to serve as a catalyst to efficiently and cheaply remove oxygen.
Graphene’s exotic properties can be tailored by cutting large sheets down to ribbons of specific lengths and edge configurations. But this “top-down” fabrication approach is not yet practical, because current lithographic techniques always produce defects. Now, scientists from the U.S. and Japan have discovered a new “bottom-up” self-assembly method for producing defect-free graphene nanoribbons with periodic zigzag-edge regions.
As in Alice’s journey through the looking-glass to Wonderland, mirrors in the real world can sometimes behave in surprising and unexpected ways, including a new class of mirror that works like no other. Scientists have demonstrated, for the first time, a new type of mirror that forgoes a familiar shiny metallic surface and instead reflects infrared light by using an unusual magnetic property of a non-metallic metamaterial.
Researchers in Japan have developed a new yet simple technique called "diffusion driven layer-by-layer assembly" to construct graphene into porous 3-D structures for applications in devices such as batteries and supercapacitors. The new method borrowed a principle from polymer chemistry, known as interfacial complexation, to allow graphene oxide to form a stable composite layer with an oppositely charged polymer.