When metallic lithium forms and deposits during the charging process in a lithium-ion battery, it can lead to a reduced battery lifespan and even short circuits. Using neutron beams, scientists have now peered into the inner workings of a functioning battery without destroying it. In the process, they have resolved this so-called lithium plating mystery.
Scientists have tapped oil and water to create scaffolds of self-assembling, synthetic proteins called peptoid nanosheets that mimic complex biological mechanisms and processes. The accomplishmentis expected to fuel an alternative design of the 2-D peptoid nanosheets that can be used in a broad range of applications. Among them could be improved chemical sensors and separators, and safer, more effective drug delivery vehicles.
Researchers working in synthetic organic chemistry are under pressure to quickly develop innovative chemical reactions. But with methods largely unchanged over the last 50 years, synthesis possibilities are constrained by limited temperature ranges, demanding experiment supervision and lack of repeatability. New technology is enhancing synthesis by eliminating these challenges.
In the age-old nature versus nurture debate, Douglas Clark, a faculty scientist with Lawrence Berkeley National Laboratory and the Univ. of California, Berkeley, is not taking sides. In the search for enzymes that can break lignocellulose down into biofuel sugars under the extreme conditions of a refinery, he has prospected for extremophilic microbes and engineered his own cellulases.
A fortuitous collaboration at Rice Univ. has led to the total synthesis of a recently discovered natural antibiotic. The laboratory recreation of a fungus-derived antibiotic, viridicatumtoxin B, may someday help bolster the fight against bacteria that evolve resistance to treatments in hospitals and clinics around the world.
A number of leading international researchers, among others from the National Food Institute, Technical University of Denmark, have recommended that fluorochemicals should only be used where absolutely essential, until better methods exist to measure the chemicals and more is known about their potentially harmful effects.
Only recently has it become possible to accurately “see” the structure of a liquid. Using x-rays and a high-tech apparatus that holds liquids without a container, a professor at Washington Univ. in St. Louis was able to compare the behavior of glass-forming liquids as they approach the glass transition.
Recycled tires could see new life in lithium-ion batteries that provide power to plug-in electric vehicles and store energy produced by wind and solar, say researchers at Oak Ridge National Laboratory. By modifying the microstructural characteristics of carbon black, a substance recovered from discarded tires, a team of researchers is developing a better anode for lithium-ion batteries.
For tiny fractions of a second, when illuminated by a laser pulse, quartz glass can take on metallic properties. The phenomenon, recently revealed by large-scale computer simulations, frees electrons, allowing quartz to become opaque and conduct electricity. The effect could be used to build logical switches which are much faster than today’s microelectronics.
Polymers come with a range of properties dictated by their chemical composition and geometrical arrangement. Yasuyuki Tezuka and his team at Tokyo Institute of Technology have now applied an approach to synthesize a new type of multicyclic polymer geometry. While mathematicians are interested because these structures have not been realized before, the geometry studies also provide insights for chemists.
There’s an old saying in the biofuels industry: “You can make anything from lignin except money.” But now, a new study may pave the way to challenging that adage. The study from the National Renewable Energy Laboratory demonstrates a concept that provides opportunities for the successful conversion of lignin into a variety of renewable fuels, chemicals, and materials for a sustainable energy economy.
Findings from a physics study by a Kansas State Univ. researcher are helping scientists accurately predict the once unpredictable. They looked at theoretically predicting and understanding chemical reactions that involve three atoms at ultracold temperatures. Their findings help explain the likely outcome of a chemical reaction and shed new light on mysterious quantum states.
There’s a certain type of biomolecule built like a nano-Christmas tree. Called a glycoconjugate, it’s many branches are bedecked with sugary ornaments. It’s those ornaments that get all the glory. That’s because, according to conventional wisdom, the glycoconjugate’s lowly “tree” basically holds the sugars in place as they do the important work of reacting with other molecules.
A mechanical engineering student at EPFL in Switzerland wanted to understand the reason behind the formation of a “foam volcano” after tapping the neck of a bottle of beer. He studied the phenomenon with a high-speed camera and compared it to the outcome of applying the same action to sparkling water. His work offers insights into the behavior of cavitation nuclei.
A research team investigating an important cofactor in photosynthesis, a manganese-calcium complex which uses solar energy to split water into molecular oxygen, have determined the exact structure of this complex at a crucial stage in the chemical reaction. The new insights into how molecular oxygen is formed at this metal complex may provide a blueprint for synthetic systems that could store sunlight energy in chemical energy carriers.
Just how much Arctic permafrost will thaw in the future and how fast heat-trapping carbon dioxide will be released from those warming soils is a topic of lively debate among climate scientists. To answer those questions, scientists need to understand the mechanisms that control the conversion of organic soil carbon into carbon dioxide gas. Until now, researchers believed that bacteria were largely responsible.
The sweet and salty aroma of sunscreen and seawater signals a relaxing trip to the shore. But scientists are now reporting that the idyllic beach vacation comes with an environmental hitch. When certain sunblock ingredients wash off skin and into the sea, they can become toxic to some of the ocean’s tiniest inhabitants, which are the main course for many other marine animals.
Scientists have, for the first time, characterized so-called quantum vortices that swirl within tiny droplets of liquid helium. The research, led by scientists at Lawrence Berkeley National Laboratory, the Univ. of Southern California and SLAC National Accelerator Laboratory, confirms that helium nanodroplets are in fact the smallest possible superfluidic objects and opens new avenues for studying quantum rotation.
In 2015, American consumers will finally be able to purchase fuel cell cars from Toyota and other manufacturers. Although touted as zero-emissions vehicles, most of the cars will run on hydrogen made from natural gas, a fossil fuel that contributes to global warming. Now scientists at Stanford Univ. have developed a low-cost, emissions-free device that uses an ordinary AAA battery to produce hydrogen by water electrolysis.
Printing whole new organs for transplants sounds like something out of a sci-fi movie, but the real-life budding technology could one day make actual kidneys, livers, hearts and other organs for patients who desperately need them. In Langmuir, scientists are reporting new understanding about the dynamics of 3-D bioprinting that takes them a step closer to realizing their goal of making working tissues and organs on-demand.
Researchers from North Carolina State Univ. have developed a novel and versatile modeling strategy to simulate polyelectrolyte systems. The model has applications for creating new materials as well as for studying polyelectrolytes, including DNA and RNA. Polyelectrolytes are chains of molecules that are positively or negatively charged when placed in water.
As anyone who has bitten into a chili pepper knows, its burning spiciness—though irresistible to some—is intolerable to others. Scientists exploring the chili pepper’s effect are using their findings to develop a new drug candidate for many kinds of pain, which can be caused by inflammation or other problems. They reported their progress on the compound, which is being tested in clinical trials, in the Journal of Medicinal Chemistry.
Trying to understand the chemistry that turns plant material into the same energy-rich gasoline and diesel we put in our vehicles, researchers have discovered that water in the conversion process helps form an impurity which, in turn, slows down key chemical reactions. The study, which was reported online at the Journal of the American Chemical Society, can help improve processes that produce biofuels from plants.
Earth’s magnetic field, a familiar directional indicator over long distances, is routinely probed in applications ranging from geology to archaeology. Now it has provided the basis for a technique which might, one day, be used to characterize the chemical composition of fluid mixtures in their native environments.
Massachusetts Institute of Technology chemical engineers have devised a new implantable tissue scaffold coated with bone growth factors that are released slowly over a few weeks. When applied to bone injuries or defects, this coated scaffold induces the body to rapidly form new bone that looks and behaves just like the original tissue.