With a chemical “trick”, scientists in Germany have succeeded in isolating a stable gold carbene complex. Experts have been proposing gold carbenes as essential short-lived intermediates in catalytic reactions, but they elude study because of their high reactivity. Chemist Prof. Dr. Bernd F. Straub and his team are the first to have created the basis for directly examining the otherwise unstable gold-carbon double bond.
Scientists analyzing data from NASA’s Cassini mission have firm evidence the ocean inside Saturn's largest moon, Titan, might be as salty as the Earth's Dead Sea. The new results come from a study of gravity and topography data collected during Cassini's repeated flybys of Titan during the past 10 years. The finding may change some scientists' expectations for present-day life on the distant moon.
For billions of years, bacteria have moved themselves using cilia. Now, researchers have constructed molecules that imitate these tiny, hair-like structures. The innovation was possible by nanofabricating artificial cilia that would respond in just one direction to provide a net displacement of motion.
The Fourth of July means millions of Americans will soon enjoy eye-popping fireworks displays around the country. These dazzling light shows are actually carefully crafted chemical reactions. A Reactions video from the American Chemical Society this week features John Conkling, Ph.D., the professor who literally wrote the book on pyrotechnics. In the video, Conkling explains the chemistry that creates those amazing fireworks displays.
Scientists are shedding new light on how invasion by exotic plant species affects the ability of soil to store greenhouse gases. New research shows that invasive plants can accelerate the greenhouse effect by releasing carbon stored in soil into the atmosphere. Since soil stores more carbon than both the atmosphere and terrestrial vegetation combined, agricultural land management could dramatically affect carbon storage.
Researchers at Princeton Univ. joined with experts at Liquid Light Inc. to devise an efficient method for harnessing sunlight to convert carbon dioxide into a potential alternative fuel known as formic acid. This type of acid is already being explored as an alternative in fuel cells. The new process takes place inside an electrochemical cell, which consists of metal plates the size of lunch-boxes that enclose liquid-carrying channels.
Experts don't fully understand how “plastic” solar panels work, which complicates the improvement of their cost efficiency and hinders wider use of the technology. However, an international team has now determined how light beams excite the chemicals in solar panels, enabling them to produce charge. Their findings were made possible with the use of femtosecond Raman spectroscopy.
Whenever there is a major spill of oil into water, the two tend to mix into a suspension of tiny droplets, called an emulsion, that is extremely hard to separate and can cause severe damage to ecosystems. A new membrane developed by Massachusetts Institute of Technology researchers can separate even these highly mixed fine oil-spill residues.
Researchers at Lawrence Berkeley National Lab and the Univ. of Hawaii have uncovered the first step in the process that transforms gas-phase molecules into solid particles like soot and other carbon-based compounds. The finding could help combustion chemists make more-efficient, less-polluting fuels and help materials scientists fine-tune their carbon nanotubes and graphene sheets for faster, smaller electronics.
An international team of physicists including researchers from the U.S. Naval Research Laboratory has used a scanning tunneling microscope to create quantum dots with identical, deterministic sizes. The perfect reproducibility of these dots opens the door to quantum dot architectures completely free of uncontrolled variations, an important goal for technologies from nanophotonics to quantum information processing.
Using world’s most powerful x-ray laser at the Linac Coherent Light Source in California, scientists have been watching as buckyballs disintegrate completely in less than 100 femtoseconds under the force of the powerful free-electron laser flashes. The study told them something important, too: they can theoretically and reliable predict the way these miniature soccer balls will explode. This is important for simulation efforts.
At the nanoscale, where objects are measured in billionths of meters and events transpire in trillionths of seconds, things do not always behave as our experiences with the macro world might lead us to expect. Water, for example, seems to flow much faster within carbon nanotubes than classical physics says should be possible. Now imagine trying to capture movies of these almost imperceptibly small nanoscale movements.
By fusing together the concepts of active fiber sensors and high-temperature fiber sensors, a team of researchers at the Univ. of Pittsburgh has created an all-optical high-temperature sensor for gas flow measurements that operates at record-setting temperatures above 800 C. The new technology should be ideal for use in deep drilling operations, nuclear reactor cores and outer space.
Rice Univ. chemical engineer Michael Wong has spent a decade amassing evidence that palladium-gold nanoparticles are excellent catalysts for cleaning polluted water, but even he was surprised at how well the particles converted biodiesel waste into valuable chemicals.
By combining advanced mathematics with high-performance computing, scientists have developed a tool that allowed them to calculate a fundamental property of most atoms on the periodic table to historic accuracy, reducing error by a factor of a thousand in many cases. The technique also could be used to determine a host of other atomic properties important in fields like nuclear medicine and astrophysics.
The chemical makeup of wastewater generated by “hydrofracking” could cause the release of tiny particles in soils that often strongly bind heavy metals and pollutants, exacerbating the environmental risks during accidental spills, Cornell Univ. researchers have found.
Testing for cocaine and other drugs usually involves two steps: a quick on-site prescreen, and then a more accurate confirmatory test at a distant laboratory. This process can take days or weeks—but that’s too long in many cases where public safety is at risk. Now, researchers report development of a backpack-sized device that can perform highly accurate and sensitive tests anywhere within 15 min.
Researchers at the Joint BioEnergy Institute (JBEI) have unveiled the first glycosyltransferase clone collection specifically targeted for the study of the biosynthesis of plant cell walls. The idea behind “the JBEI GT Collection” is to provide a functional genomic resource for researchers seeking to extract the sugars in plant biomass and synthesize them into clean, green and renewable transportation fuels.
Rice Univ. scientists have created a one-step process for producing highly efficient materials that let the maximum amount of sunlight reach a solar cell. The Rice laboratory of chemist Andrew Barron found a simple way to etch nanoscale spikes into silicon that allows more than 99% of sunlight to reach the cells’ active elements, where it can be turned into electricity.
Researchers at the Univ. of Michigan have obtained the first 3-D snapshots of the "assembly line" within microorganisms that naturally produces antibiotics and other drugs. Understanding the complete structure and movement within the molecular factory gives investigators a solid blueprint for redesigning the microbial assembly line to produce novel drugs of high medicinal value.
The inks on historical documents can hold many secrets about the past. And knowing how the ink breaks down can help scientists preserve valuable treasures. In a recent study, researchers report how a analysis method called tip-enhanced Raman spectroscopy has been developed to help identify many types of inks on various papers and other surfaces.
Nanoparticles are becoming ubiquitous in food packaging, personal care products and are even being added to food directly. But the health and environmental effects of these tiny additives have remained largely unknown. A new study now suggests that nanomaterials in food and drinks could interfere with digestive cells and lead to the release of the potentially harmful substances to the environment.
A research group at NIST has demonstrated a new method for detecting ignitable liquids that could change the way arson fires are investigated. The new process for analyzing debris for traces of fire accelerants is faster and more accurate than conventional methods and produces less waste.
Sweaty hands can reduce the effectiveness of bacteria-fighting brass objects in hospitals and schools after just an hour of coming into contact with them, according to scientists at the Univ. of Leicester. While copper found in everyday brass items has an antimicrobial effect on bacteria the team has discovered that peoples’ sweat can produce sufficient corrosion to adversely affect its use to kill a range of microorganisms.
The term “crowdsourcing” was coined in 2006 and since then has seen its definition broadened to a wide range of activities involving a network of people. A challenging problem that might benefit from crowdsourcing, according to recently published research, is the phase problem in x-ray crystallography. Retrieving the phase information has plagued many scientists for decades when trying to determine the crystal structure of a sample.