Chemists at The Scripps Research Institute and the Shanghai Institute of Organic Chemistry have described a method for creating and modifying organic compounds that overcomes a major limitation of previous methods. The advance opens up a large number of novel chemical structures for synthesis and evaluation, for example, as candidate pharmaceuticals.
Photosynthesis is probably the most well-known aspect of plant biochemistry. It enables plants, algae and select bacteria to transform the energy from sunlight during the daytime into chemical energy in the form of sugars and starches (as well as oils and proteins), and it involves taking in carbon dioxide from the air and releasing oxygen derived from water molecules.
Scientists believe that until about 2.4 billion years ago there was little oxygen in the atmosphere. Evidence in support of this hypothesis comes from studies of sulfur isotopes preserved in the rock record. But the sulfur isotope story has been uncertain because of the lack of key information that has now been provided by a new analytical technique developed by a team of Caltech geologists and geochemists.
The Earth’s ancient oceans held much lower concentrations of sulfate— a key biological nutrient— than previously recognized, according to new research.
Researchers led by David Thompson, president of Aten Biotherapeutics and a professor in Purdue's Department of Chemistry, are developing controlled-release imaging agents that allow for a longer, safer imaging session.
From water marks to colored threads, governments are constantly adding new features to paper money to stay one step ahead of counterfeiters. Now a longhorn beetle has inspired yet another way to foil cash fraud, as well as to produce colorful, changing billboards and art displays. In ACS Nano, researchers report a new kind of ink that mimics the beetle’s color-shifting ability in a way that would be long-lasting and difficult to copy.
Plants bask in the sun and need its light to live, but they also coat themselves in a natural sunscreen like a sunbather on the beach, protecting themselves from damaging rays. A new study examined the properties and mechanics of the molecule plants use to absorb harmful ultraviolet-B radiation, and its SPF rating would be off the charts.
Univ. of Utah engineers developed the first room-temperature fuel cell that uses enzymes to help jet fuel produce electricity without needing to ignite the fuel. These new fuel cells can be used to power portable electronics, off-grid power and sensors. A study of the new cells appears online in ACS Catalysis.
Scientists disclosed a new method to convert lignin, a biomass waste product, into simple chemicals. The innovation is an important step toward replacing petroleum-based fuels and chemicals with biorenewable materials. Lignin is the substance that makes trees and cornstalks sturdy, and it accounts for nearly 30% of the organic carbon in the biosphere.
Researchers in Germany have employed micro-FTIR and ATR-FTIR spectroscopy to determine precisely the type and source of microplastics found in the wastewater of a regional water association in Lower Saxony. With these infrared imaging methods, it is now possible to specifically classify plastics, such as those used in toothpaste, cosmetics, fleece jackets and packaging.
A new membrane, developed scientists in the Netherlands, can be made more or less porous “on demand”. In this way, smart switching between “open” and “closed” is possible, which opens the way to innovative applications in biosensors, chemical analysis and catalysis.
Scientists have long speculated as to why animal species didn’t flourish sooner, once sufficient oxygen covered the Earth’s surface. Animals began to prosper at the end of the Proterozoic period, about 800 million years ago. But what about the billion-year stretch before that, when most researchers think there also was plenty of oxygen? Well, it seems the air wasn’t so great then, after all.
With fears growing over chemical and biological weapons falling into the wrong hands, scientists are developing microrockets to fight back against these dangerous agents, should the need arise. In ACS Nano, they describe new spherical micromotors that rapidly neutralize chemical and biological agents and use water as fuel.
An overwhelming number of chemicals from household and industrial products are in the environment, and hundreds are in our bodies. But for most of them, scientists have yet to determine whether they cause health problems. Now they’ve taken the first step toward doing that by estimating which substances people are exposed to the most.
DEET has been the gold standard of insect repellents for more than six decades, and now researchers led by a Univ. of California, Davis, scientist have discovered the exact odorant receptor that repels them. They also have identified a plant defensive compound that might mimic DEET, a discovery that could pave the way for better and more affordable insect repellents.
Researchers with CiQUS in Spain have developed a new method to overcome limitations of surface enhanced Raman spectroscopy (SERS), an ultra-sensitive analytical technique able to detect chemicals in very low concentration. The research results show how to cut production costs of substrates and also tackle the lack of reproducibility usually associated to this technique.
Researchers at McGill Univ. have succeeded in simultaneously observing the reorganizations of atomic positions and electron distribution during the transformation of the “smart material” vanadium dioxide from a semiconductor into a metal. The observations are made in a time frame a trillion times faster than the blink of an eye.
Nitrogen is an essential component of all living systems, playing important roles in everything from proteins and nucleic acids to vitamins. It is the most abundant element in Earth's atmosphere and is literally all around us, but in its gaseous state, N2, it is inert and useless to most organisms.
Rice Univ. researchers have delivered a scientific one-two punch with a pair of papers that detail how synthetic collagen fibers self-assemble via their sticky ends. Collagen is the most common protein in mammals, a major component of bone and the fibrous tissues that support cells and hold organs together. Discovering its secrets may lead to better synthetic collagen for tissue engineering and cosmetic and reconstructive medicine.
Scientists in Europe have developed a chemical “processor” which reliably shows the fastest way through a city maze. Because the method is basically faster than a satellite navigation system, it could be useful in transport planning and logistics in the future, for instance.
In early drug discovery, you need a starting point. In a new research paper published in PLOS-Neglected Tropical Diseases, a team of researchers present hundreds of such starting points for potentially treating Human African trypanosomiasis, or sleeping sickness, a deadly disease that affects thousands of people annually.
Researchers at Virginia Commonwealth Univ. have discovered that most of the electrolytes used in lithium-ion batteries are superhalogens, and that the vast majority of these electrolytes contain toxic halogens. At the same time, the researchers also found that the electrolytes in lithium-ion batteries could be replaced with halogen-free electrolytes that are both nontoxic and environmentally friendly.
Researchers in the U.K. have found a new way to make nanostructured carbon using the waste product sawdust. By cooking sawdust with a thin coating of iron at 700 C, they have discovered that they can create carbon with a structure made up of many tiny tubes. These tubes are one thousand times smaller than an average human hair.
Helium is a famously unreactive gas but when cooled to just above absolute zero it becomes a superfluid, a strange form of liquid. An Anglo-Austrian team has used this liquid to develop a completely new way of forming charged particles. The team’s key discovery is that helium atoms can acquire an excess negative charge which enables them to become aggressive new chemical reagents.
For as long as scientists have been able to create new proteins that are capable of self-assembling into fibers, scientists’ work has taken place on the nanoscale. For the first time, this achievement has been realized on the microscale, a leap of magnitude in size that presents significant new opportunities for using engineered protein fibers.