A means by which the removal of carbon dioxide from coal-fired power plants might one day be done far more efficiently and at far lower costs than today has been discovered by a team of researchers with the Lawrence Berkeley National Laboratory. By appending a diamine molecule to the sponge-like solid materials known as MOFs, the researchers were able to more than triple the carbon dioxide-scrubbing capacity of the MOFs.
Repeatability underlies a researcher’s ability to control variation and increase sensitivity in an experiment. For sensitive analyses, such as cell-based assays, mass spectrometry and high-resolution protein structure determination, precise repeatability requires careful factorial design of experiments by systematically varying experimental parameters.
Univ. of New South Wales Australia scientists have developed a highly efficient oxygen-producing electrode for splitting water that has the potential to be scaled up for industrial production of the clean energy fuel, hydrogen. The new technology is based on an inexpensive, specially coated foam material that lets the bubbles of oxygen escape quickly.
One of life's strongest bonds has been discovered by a science team researching biofuels with the help of supercomputers. Their find could boost efforts to develop catalysts for biofuel production from non-food waste plants.
Research led by a Brown Univ. graduate student has revealed a new way to make light-absorbing perovskite films for use in solar cells. The new method involves a room-temperature solvent bath to create perovskite crystals, rather than the blast of heat used in current crystallization methods.
Liquid chromatography-mass spectrometry (LC-MS) is taking over as an analytical technique of choice in diverse fields. While a LC-MS analyst may be tempted to rely on the most commonly used sample prep techniques, columns and mobile phases in his/her field, we show successful LC-MS demands these workflow elements be chosen with the physico-chemical properties of the analyte in mind.
The pistons in your car engine rub up against their cylinder walls thousands of times a minute; without lubrication in the form of motor oil, they and other parts of the engine would quickly wear away, causing engine failure. Motor oil contains chemical additives that extend how long engines can run without failure, but, despite decades of ubiquity, how such additives actually work to prevent this damage have remained a mystery.
As with magnets and alternating current, positively charged molecules never aim for one another. Indeed, similarly charged poles are repelled. Nevertheless, a team from the Univ. of Copenhagen managed to become the first to bond positively charged phosphorus atoms with positively charged hydrogen ones. Their insight may prove pivotal to understanding how biologically important molecules such as DNA and proteins form properly.
For the last seven years, Yale Univ. graduate student Staff Sheehan has been working on splitting water. Now, a paper published in Nature Communications reveals how one of the methods he and his team have uncovered for this process, using a specific iridium species as a water oxidation catalyst, could aid in the development of renewable fuels.
Unique proteins newly discovered in heat-loving bacteria are more than capable of attaching themselves to plant cellulose, possibly paving the way for more efficient methods of converting plant matter into biofuels. The unusual proteins, called tapirins, bind tightly to cellulose, a key structural component of plant cell walls, enabling these bacteria to break down cellulose.
A new molecule-making machine could do for chemistry what 3-D printing did for engineering: Make it fast, flexible and accessible to anyone. Chemists at the Univ. of Illinois built the machine to assemble complex small molecules at the click of a mouse, like a 3-D printer at the molecular level. The automated process has the potential to greatly speed up and enable new drug development and other technologies that rely on small molecules.
Univ. of California, Berkeley chemists have made a major leap forward in carbon-capture technology with a material that can efficiently remove carbon from the ambient air of a submarine as readily as from the polluted emissions of a coal-fired power plant. The material then releases the carbon dioxide at lower temperatures than current carbon-capture materials.
The editors of R&D Magazine have announced an eligibility extension for products to be entered into the 2015 R&D 100 Awards. The 2015 R&D 100 Awards will honor products, technologies and services that have been introduced to the market between January 1, 2014 and March 31, 2015.
In a study published in Nature Chemistry, Univ. of Wisconsin-Madison chemistry Prof. Kyoung-Shin Choi presents a new approach to combine solar energy conversion and biomass conversion, two important research areas for renewable energy. For decades, scientists have been working to harness the energy from sunlight to drive chemical reactions to form fuels such as hydrogen, which provide a way to store solar energy for future use.
New York Univ. chemists have developed a computational approach for determining the viability and suitability of complex molecular structures—an advancement that could aid in the development of pharmaceuticals as well as a range of other materials.
Lithium-ion batteries are common in consumer electronics. Beyond consumer electronics, lithium-ion batteries have also grown in popularity for military, electric vehicle and aerospace applications. Now, researchers at Arizona State Univ. are exploring new energy storage technology that could give the battery an even longer lifecycle.
When it comes to boiling water, is there anything left for today’s scientists to study? The surprising answer is, yes, quite a bit. How the bubbles form at a surface, how they rise up and join together, what are the surface properties, what happens if the temperature increases slowly versus quickly. While these components might be understood experimentally, the mathematical models for the process of boiling are incomplete.
Methane is a potent greenhouse gas, second only to carbon dioxide in its capacity to trap heat in Earth’s atmosphere for a long time. The gas can originate from lakes and swamps, natural-gas pipelines, deep-sea vents and livestock. Understanding the sources of methane, and how the gas is formed, could give scientists a better understanding of its role in warming the planet.
Trapping carbon dioxide emissions from power plants and various industries could play a significant role in reducing greenhouse gas emissions in the future. But current materials that can collect carbon dioxide have low capacities or require very high temperatures to work. Scientists are making progress toward a more efficient alternative, described in Chemistry of Materials, that could help make carbon capture less energy intensive.
Researchers with the Energy Biosciences Institute have found a way to increase the production of fuels and other chemicals from biomass fermented by yeast. By introducing new metabolic pathways into the yeast, they enable the microbes to efficiently ferment cellulose and hemicellulose, the two major families of sugar found in the plant cell wall, without the need of environmentally harsh pre-treatments or expensive enzyme cocktails.
The concept of randomness appears across scientific disciplines, from materials science to molecular biology. Now, theoretical chemists at Princeton Univ. have challenged traditional interpretations of randomness by computationally generating random and mechanically rigid arrangements of 2-D hard disks, such as pennies, for the first time.
A new provisionally patented technology from a New Mexico State Univ. researcher could revolutionize carbon dioxide capture and have a significant impact on reducing pollution worldwide. Through research on zeolitic imidazolate frameworks, or ZIFs, the researcher synthesized a new subclass of ZIF that incorporates a ring carbonyl group in its organic structure.
Fans of the popular TV series “CSI” know that the forensics experts who investigate crime scenes are looking for answers to three key questions: “Who did it; how did they do it; and can we stop them from doing it again?” The field of nuclear forensics, an important element of Lawrence Livermore National Laboratory’s national security mission, has similar goals and uses similar techniques, but with even higher stakes.
A new study from the National Renewable Energy Laboratory demonstrates the conversion of lignin-derived compounds to adipic acid, an important industrial dicarboxylic acid produced for its use as a precursor to nylon. The demonstration is an important step toward the goal of garnering more uses from lignin, which could be crucial for the economic success of the biofuels industry.
Researchers from institutions including Lund Univ. have taken a step closer to producing solar fuel using artificial photosynthesis. In a new study, they have successfully tracked the electrons' rapid transit through a light-converting molecule. The ultimate aim of the present study is to find a way to make fuel from water using sunlight.