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Eco-friendly pre-fab nanoparticles could advance nanomanufacturing

August 13, 2014 11:21 am | by Janet Lathrop, UMass Amherst | News | Comments

A team of materials chemists, polymer scientists, device physicists and others at the Univ. of Massachusetts Amherst report a breakthrough technique for controlling molecular assembly of nanoparticles over multiple length scales that should allow faster, cheaper, more ecologically friendly manufacture of organic photovoltaics and other electronic devices.

“Shape-shifting” material could help reconstruct faces

August 13, 2014 8:49 am | News | Comments

Injuries, birth defects (such as cleft palates) or surgery to remove a tumor can create gaps in bone that are too large to heal naturally. And when they occur in the head, face or jaw, these bone defects can dramatically alter a person’s appearance. Researchers have developed a “self-fitting” material that expands with warm salt water to precisely fill bone defects, and also acts as a scaffold for new bone growth.

Copper foam turns CO2 into useful chemicals

August 13, 2014 8:21 am | by Kevin Stacey, Brown Univ. | News | Comments

A catalyst made from a foamy form of copper has vastly different electrochemical properties from catalysts made with smooth copper in reactions involving carbon dioxide, a new study shows. The research, by scientists in Brown Univ.’s Center for the Capture and Conversion of CO2, suggests that copper foams could provide a new way of converting excess CO2 into useful industrial chemicals.

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NC State partners with Bio2Electric on new catalyst technology

August 13, 2014 8:11 am | by Matt Shipman, News Services, North Carolina State Univ. | News | Comments

North Carolina State Univ. is part of a project team that is researching and developing new catalyst technology to produce the commercially important chemicals ethylene and propylene from natural gas. The project lead, Bio2Electric, LLC, dba EcoCatalytic Technologies, is collaborating with North Carolina State Univ., among other industry partners, to develop the new catalyst technologies.

Foam favorable for oil extraction

August 13, 2014 7:49 am | by Mike Williams, Rice Univ. | Videos | Comments

A Rice Univ. laboratory has provided proof that foam may be the right stuff to maximize enhanced oil recovery (EOR). In tests, foam pumped into an experimental rig that mimicked the flow paths deep underground proved better at removing oil from formations with low permeability than common techniques involving water, gas, surfactants or combinations of the three.

New analysis reveals tumor weaknesses

August 13, 2014 7:40 am | by Anne Trafton, MIT News Office | News | Comments

Scientists have known for decades that cancer can be caused by genetic mutations, but more recently they have discovered that chemical modifications of a gene can also contribute to cancer. These alterations, known as epigenetic modifications, control whether a gene is turned on or off. Analyzing these modifications can provide important clues to the type of tumor a patient has, and how it will respond to different drugs.

Could hemp nanosheets topple graphene for making the ideal supercapacitor?

August 12, 2014 12:34 pm | News | Comments

As hemp makes a comeback in the U.S. after a decades-long ban on its cultivation, scientists are reporting that fibers from the plant can pack as much energy and power as graphene, long-touted as the model material for supercapacitors. A team has figured out how to make electrodes from certain hemp fibers, and the breakthrough came from figuring out how to process them.

Six nines: Ultra-enriched silicon paves the road to quantum computing

August 12, 2014 12:27 pm | News | Comments

Using a relatively straightforward technique, a team of NIST researchers has created what may be the most highly enriched silicon currently being produced. The material is more than 99.9999% pure silicon-28, with less than 1 part per million (ppm) of the problematic isotope silicon-29. Many quantum computing schemes require isotopically pure silicon, for example to act as a substrate for qubits.

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New Nano3 microscope will allow high-resolution look inside cells

August 12, 2014 12:14 pm | News | Comments

The Univ. of California, San Diego’s Nanofabrication Cleanroom Facility (Nano3) is the first institution to obtain a new FEI Scios dual-beam microscope, with an adaptation for use at cryogenic temperatures. The new microscope allows biologists to nanomachine cells to reduce them to the thickness required for electron microscopy without creating any sample distortions and while maintaining cryogenic temperatures.

Water’s reaction with metal oxides opens doors for researchers

August 11, 2014 8:00 am | by Scott Gordon, Univ. of Wisconsin-Madison | News | Comments

A multi-institutional team has resolved a long-unanswered question about how two of the world’s most common substances interact. In a paper published recently in Nature Communications, an international team reported fundamental discoveries about how water reacts with metal oxides. The paper opens doors for greater understanding and control of chemical reactions in fields ranging from catalysis to geochemistry and atmospheric chemistry.

Database accelerates the development of new materials

August 8, 2014 2:05 pm | News | Comments

Performing systematic analyses of both known and imagined chemical compounds to find their key properties, Northwestern Univ. engineers have created a database that takes some of the guesswork out of designing new materials. Called the Open Quantum Materials Database (OQMD), it launched in November and is the largest database in the world of its kind, containing analyses of 285,780 compounds and growing.

Catching chemistry in motion

August 7, 2014 8:02 am | by SLAC Office of Communications | News | Comments

Researchers at SLAC National Accelerator Laboratory have developed a laser-timing system that could allow scientists to take snapshots of electrons zipping around atoms and molecules. Taking timing to this new extreme of speed and accuracy at the Linac Coherent Light Source x-ray laser will make it possible to see the formative stages of chemical reactions.

Enhanced Sample Prep

August 6, 2014 9:21 am | by Lindsay Hock, Managing Editor | Articles | Comments

Sample preparation is a critical step in the analytical process. Studies report that sample prep can represent about 60% of a laboratory technician’s time and also forms one of the principal sources of error. Many techniques to conduct sample prep are available to researchers, such as filtration, digestion, dialysis, liquid/liquid extraction and solid phase extraction.

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A breath reveals anti-counterfeit drug labels

August 6, 2014 7:48 am | by Kate McAlpine, Univ. of Michigan | News | Comments

An outline of Marilyn Monroe's iconic face appeared on the clear, plastic film when a researcher fogs it with her breath. Terry Shyu, a doctoral student in chemical engineering at the Univ. of Michigan, was demonstrating a new high-tech label for fighting drug counterfeiting. While the researchers don't envision movie stars on medicine bottles, they used Monroe's image to prove their concept.

The atomic picture of magnetism

August 5, 2014 10:05 pm | News | Comments

The search for zero-resistance conductors that can operate at realistic temperatures has been frustrated by the inability to understand high-temperature superconductors, particularly their magnetic structure. Researchers have done this at the atomic scale for the first time with a so-called strongly correlated electron system of iron telluride. Previously, magnetic information was provided by neutron diffraction, which is imprecise.

The perfect atom sandwich requires an extra layer

August 5, 2014 11:21 am | by Anne Ju, Cornell Univ. | News | Comments

Like the perfect sandwich, a perfectly engineered thin film for electronics requires not only the right ingredients, but also just the right thickness of each ingredient in the desired order, down to individual layers of atoms. In recent experiments Cornell Univ. researchers found a major difference between assembling atomically precise oxide films and the conventional layer-by-layer “sandwich making” of molecular beam epitaxy.

Used-cigarette butts offer energy storage solution

August 5, 2014 11:08 am | News | Comments

A group of scientists from South Korea have converted used-cigarette butts into a high-performing material that could be integrated into computers, handheld devices, electrical vehicles and wind turbines to store energy. In published research, the team has demonstrated that the cellulose acetate fibres that cigarette filters are mostly composed of could be transformed into a carbon-based material using pyrolysis.

“SuperCam” instrument adds capabilities to successful ChemCam

August 4, 2014 12:32 pm | News | Comments

Laser technology originally developed at Los Alamos National Laboratory for the Mars Science Laboratory has been selected for NASA’s new Mars mission in 2020. The Curiosity rover is equipped with ChemCam, which allows researchers to sample rocks and other targets from a distance using a laser. The new “SuperCam” will offer this capability along with another spectrum for Raman and time-resolved fluorescence spectroscopy.

Scientists solve 2,000-year-old Terracotta Army mystery

August 4, 2014 10:12 am | News | Comments

China's first emperor ordered the building of a glorious underground palace complex, mirroring his imperial capital, that would last for an eternity. Protecting this underworld palace was his imperial guard, cast in terracotta. Efforts to preserve the 1974 archaeological find have been hampered by failures to pinpoint the binding material used in applying pigments to the soldiers. Mass spectrometry studies have recently solved this mystery.

“Wetting” a battery’s appetite for renewable energy storage

August 4, 2014 9:22 am | by Frances White, PNNL | Videos | Comments

Sun, wind and other renewable energy sources could make up a larger portion of the electricity America consumes if better batteries could be built to store the intermittent energy for cloudy, windless days. Now a new material could allow more utilities to store large amounts of renewable energy and make the nation's power system more reliable and resilient.

Study of aerosols stands to improve climate models

August 4, 2014 9:12 am | by Kimm Fesenmaier, Caltech | News | Comments

Aerosols, tiny particles in the atmosphere, play a significant role in Earth's climate, scattering and absorbing incoming sunlight and affecting the formation and properties of clouds. Currently, the effect that these aerosols have on clouds represents the largest uncertainty among all influences on climate change.

NASA to test making rocket fuel on Mars

August 4, 2014 8:16 am | News | Comments

Taking fuel to Mars for return flights is heavy and expensive. The $1.9 billion Mars 2020 rover that NASA announced on Friday will include an experiment that will turn carbon dioxide in the Martian atmosphere into oxygen. It could then be used to make rocket fuel and for future astronauts to breathe. The device, named MOXIE, will make about three-quarters of an ounce of oxygen an hour.

Self-assembling anti-cancer molecules created in minutes

August 4, 2014 7:53 am | by Tom Frew, International Press Officer, Univ. of Warwick | News | Comments

Researchers have developed a simple and versatile method for making artificial anti-cancer molecules that mimic the properties of one of the body’s natural defense systems. The chemists have been able to produce molecules that have a similar structure to peptides which are naturally produced in the body to fight cancer and infection.

Chemists demonstrate “bricks-and-mortar” assembly of new molecular structures

July 31, 2014 10:16 am | News | Comments

Scientists in Indiana have recently described the self-assembly of large, symmetrical molecules in “bricks-and-mortar” fashion. While researchers have created many such large, cyclic molecules, or macrocycles, what these chemists have built is a cyanostar, a five-sided molecule that is unusual in that it can be readily synthesized in a "one pot" process. It also has an unprecedented ability to bind with large, negatively charged anions.

Toward a home test for detecting potentially dangerous levels of caffeine

July 31, 2014 8:37 am | by American Chemical Society | News | Comments

The shocking news of an Ohio teen who died of a caffeine overdose in May highlighted the potential dangers of the normally well-tolerated and mass-consumed substance. To help prevent serious health problems that can arise from consuming too much caffeine, scientists are reporting progress toward a rapid, at-home test to detect even low levels of the stimulant in most beverages and even breast milk.

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