A gas that gives rotten eggs their distinctive odor could one day form the basis of new cardiovascular therapies. Research has indicated that a new compound, called AP39, which generates minute quantities of the gas hydrogen sulfide inside cells, could be beneficial in cases of high blood pressure and diseases of the blood vessels that occur with aging and diabetes.
A rule proposed by the Environmental Protection Agency that aims to curb emissions from oil...
In today’s world, in which the threat of terrorism looms, there is an urgent need for fast,...
New battery technology from the Univ. of Michigan should be able to prevent the kind of fires that grounded Boeing 787 Dreamliners in 2013. The innovation is an advanced barrier between the electrodes in a lithium-ion battery. Made with nanofibers extracted from Kevlar, the tough material in bulletproof vests, the barrier stifles the growth of metal tendrils that can become unwanted pathways for electrical current.
Coating the mouth with BPA-containing food does not lead to higher than expected levels of BPA in blood, according to a new study. The study concludes that oral exposure does not create a risk for high exposures. BPA, also known as bisphenol A, is used to make some plastics and to seal canned food containers against bacterial contamination. Food, which picks up trace amounts of BPA from packaging, is the major source of human exposure.
One way of storing solar energy is to transform the energy directly into a fuel. Researchers at Uppsala Univ. have shown a reaction which makes the process of creating fuel from solar energy more efficient and less energy demanding. Solar energy is abundant. In one hour, the Earth receives as much energy from the sun as humankind uses in a whole year.
Univ. of California, Irvine and Australian chemists have figured out how to unboil egg whites, an innovation that could dramatically reduce costs for cancer treatments, food production and other segments of the $160 billion global biotechnology industry, according to findings published in ChemBioChem.
A team of chemists at Nagoya Univ. has synthesized novel transition metal-complexed cycloparaphenylenes (CPPs) that enable selective monofunctionalization of CPPs for the first time, opening doors to the construction of unprecedented nanocarbons. The team has synthesized novel CPP chromium complexes and demonstrated their utility in obtaining monofunctionalized CPPs, which could be useful for making carbon nanotubes.
Scientists at the Univ. of York are part of a research team which has found that a recently discovered family of enzymes can degrade resistant forms of starch. Earlier research established that the enzymes, lytic polysaccharide monooxygenases (LPMOs), are able to degrade hard-to-digest biomass into its constituent sugars.
Many health advocates advise people to eat an orange and drink water rather than opt for a serving of sugary juice. But in the Journal of Agricultural and Food Chemistry, scientists report that the picture is not clear-cut. Although juice is indeed high in sugar, the scientists found that certain nutrients in orange juice might be easier for the body to absorb than when a person consumes them from unprocessed fruit.
Does glass ever stop flowing? Researchers have combined computer simulation and information theory, originally invented for telephone communication and cryptography, to answer this puzzling question. Watching a glass blower at work we can clearly see the liquid nature of hot glass. Once the glass has cooled down to room temperature though, it has become solid and we can pour wine in it or make window panes out of it.
Many of today's most promising renewable energy technologies rely upon catalysts to expedite the chemical reactions at the heart of their potential. Catalysts are materials that enhance chemical reactions without being consumed in the process. For over a century, engineers across the world have engaged in a near-continual search for ways to improve catalysts for their devices and processes.
Carbon sequestration promises to address greenhouse gas emissions by capturing carbon dioxide from the atmosphere and injecting it deep below the Earth’s surface, where it would permanently solidify into rock. The U.S. Environmental Protection Agency estimates that current carbon sequestration technologies may eliminate up to 90% of carbon dioxide emissions from coal-fired power plants.
Rice Univ. scientists have found the balance necessary to aid healing with high-tech hydrogel. The team created a new version of the hydrogel that can be injected into an internal wound and help it heal while slowly degrading as it is replaced by natural tissue. Hydrogels are used as a scaffold upon which cells can build tissue. The new hydrogel overcomes a host of issues that have kept them from reaching their potential to treat injuries.
One way of removing harmful nitrate from drinking water is to catalyze its conversion to nitrogen. This process suffers from the drawback that it often produces ammonia. By using palladium nanoparticles as a catalyst, and by carefully controlling their size, this drawback can be eliminated. It was research conducted by Yingnan Zhao of the Univ. of Twente’s MESA+ Institute for Nanotechnology that led to this discovery.
A new version of an online tool created by Argonne National Laboratory will help biofuels developers gain a detailed understanding of water consumption of various types of feedstocks, aiding development of sustainable fuels that will reduce impact on limited water resources.
Just as the invention of non-stick pans was a boon for chefs, a new type of nanoscale surface that bacteria can’t stick to holds promise for applications in the food processing, medical and even shipping industries. The technology uses an electrochemical process called anodization to create nanoscale pores that change the electrical charge and surface energy of a metal surface.
A team of chemical engineering researchers has developed a technique that uses a new catalyst to convert methane and water into hydrogen and a fuel feedstock called syngas with the assistance of solar power. The catalytic material is more than three times more efficient at converting water into hydrogen gas than previous thermal water-splitting methods.
Fear of water may seem like an irrational hindrance to humans, but on a molecular level, it lends order to the world. Some substances, in particular greasy, oily ones, are hydrophobic. They have no attraction to water, and essentially appear repelled by the stuff. Combine hydrophobic pieces in a molecule with parts that are instead attracted to water, and sides are taken. Structure appears, as in the membranes that encircle living cells.
Rice Univ. scientists advanced their recent development of laser-induced graphene by producing and testing stacked, 3-D supercapacitors, energy storage devices that are important for portable, flexible electronics. The Rice laboratory of chemist James Tour discovered last year that firing a laser at an inexpensive polymer burned off other elements and left a film of porous graphene.
Scientists at Oak Ridge National Laboratory are learning how the properties of water molecules on the surface of metal oxides can be used to better control these minerals and use them to make products such as more efficient semiconductors for organic light-emitting diodes and solar cells, safer vehicle glass in fog and frost and more environmentally friendly chemical sensors for industrial applications.
A team of chemistry and materials science experts from Univ. of California, Santa Barbara and The Dow Chemical Company has created a novel way to overcome one of the major hurdles preventing the widespread use of controlled radical polymerization.
An ultra-thin nanomaterial is at the heart of a major breakthrough by Univ. of Waterloo scientists who are in a global race to invent a cheaper, lighter and more powerful rechargeable battery for electric vehicles. Their discovery of a material that maintains a rechargable sulphur cathode helps to overcome a primary hurdle to building a lithium-sulphur battery.
Chemists have made a significant advancement to directly functionalize C-H bonds in natural products by selectively installing new carbon-carbon bonds into highly complex alkaloids and nitrogen-containing drug molecules. C-H functionalization is a much more streamlined process than traditional organic chemistry, holding the potential to greatly reduce the time and number of steps needed to create derivatives of natural products.
Outside his career as a noted nanochemist, Lawrence Berkeley National Laboratory (Berkeley Lab) director Paul Alivisatos is an avid photographer. To show off his photos, his preferred device is a Kindle Fire HDX tablet because “the color display is a whole lot better than other tablets,” he says.
Even when building big, every atom matters, according to new research on particle-based materials at Rice Univ. Rice researchers have published a study showing what happens at the nanoscale when “structurally complex” materials like concrete rub against each other. The scratches they leave behind can say a lot about their characteristics.
It has been taken for granted for over 50 years that the type of spectroscopy widely used to study hydrogen inside materials is not subject to any selection rules. In the joint theoretical and experimental study that appeared recently in Physical Review Letters, an international team of researchers showed that this near universally held view is incorrect for at least one important class of hydrogen-entrapping compounds.
Rather than soothe and comfort, a hot cup of tea or cocoa can cause people with sensitive teeth a jolt of pain. But scientists are now developing a new biomaterial that can potentially rebuild worn enamel and reduce tooth sensitivity for an extended period. They describe the material, which they tested on dogs, in ACS Nano.
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