Chemical experiments with superheavy elements, which have atomic numbers beyond 104, are extremely challenging because they must be synthesized in a particle accelerator and they decay rapidly. An international team has, for the first time, established a chemical bond between a superheavy element, in this case element 106, seaborgium, and a carbon atom. The experiment opens the door to new investigations of relativity effects.
No matter how many times it’s demonstrated, it’s still hard to envision bacteria as social,...
One sip of a perfectly poured glass of wine leads to an explosion of flavors in your mouth. Researchers in Denmark have now developed a nanosensor that can mimic what happens in your mouth when you drink wine. The sensor, which uses gold nanoparticles to act as a “mini-mouth”, measures how you experience the sensation of dryness in the wine.
Chemists at the Univ. of California, Irvine, have scored a scientific first: capturing moving images of a single molecule as it vibrates, or “breathes,” and shifts from one quantum state to another. The groundbreaking achievement, led by Ara Apkarian, professor of chemistry, and Eric Potma, associate professor of chemistry, opens a window into the strange realm of quantum mechanics.
Researchers in Russia have developed a new method for the industrial synthesis of an ultra-hard material that exceeds diamond in hardness. An article recently published in Carbon describes in detail a method that allows for the synthesis of ultrahard fullerite, a polymer composed of fullerenes, or spherical molecules made of carbon atoms.
In recent years, it has become possible to see directly individual atoms using electron microscopy, especially in graphene. Using electron microscopy and computer simulations, an international team has recently shown how an electron beam can move silicon atoms through the graphene lattice without causing damage.
The production and consumption of chemical substances threatening the ozone layer has been regulated since 1987 in the Montreal Protocol. Eight international expert reports have since been published, the most recent of which was presented on Sept. 10 at the United Nations Headquarters in New York. Model calculations reveal that by 2050 the ozone layer may return to its 1980 levels.
Bacteria secrete a mucus-like “extracellular polymeric substance” that forms biofilms, allowing bacterial colonies to thrive on surfaces. Costs associated with biofilms affecting medical devices and industrial equipment amount to billions of dollars annually. New research reveals specifics about interactions that induce bacteria to swim close to surfaces and attach to biofilms. This may point to future approaches for fighting biofilms.
Biologists claim that humans can perceive and distinguish a trillion different odors, but little is known about the underlying chemical processes involved. Biochemists at The City College of New York have found an unexpected chemical strategy employed by the mammalian nose to detect chemicals known as aldehydes.
Researchers have been trying to increase the efficiency of solid oxide fuel cells by lowering the temperatures at which they run. In a serendipitous finding at Pacific Northwest National Laboratory, researchers have created a new form of strontium-chromium oxide that performs as a semiconductor and also allows oxygen to diffuse easily, a requirement for a solid oxide fuel cell.
Despite being outlawed in 2012 in the U.S., the synthetic drugs known as “bath salts”—which really aren’t meant for your daily bath—are still readily available in some retail shops, on the Internet and on the streets. To help law enforcement, scientists are developing a novel method that could be the basis for the first portable, on-site testing device for identifying the drugs.
A new frontier for studying 2-D matter is provided by planar collections of electrons at the surface of transition-metal-oxide (TMO) materials, in which high electron densities give rise to interactions that are stronger than in semiconductors. Scientists hope to find exotic phenomena in these highly-interactive electron environments and one of the leaders in this effort is James Williams, a new fellow at the Joint Quantum Institute.
Artificial membranes mimicking those found in living organisms have many potential applications ranging from detecting bacterial contaminants in food to toxic pollution in the environment to dangerous diseases in people. Now a group of scientists in Chile has developed a way to create these delicate, ultra-thin constructs through a "dry" process, by evaporating two commercial, off-the-shelf chemicals onto silicon surfaces.
A team of scientists led by Carnegie's Jacqueline Faherty has discovered the first evidence of water ice clouds on an object outside of our own Solar System. Water ice clouds exist on our own gas giant planets, but have not been seen outside of the planets orbiting our Sun until now.
For decades, doctors have developed methods to diagnose how different types of cells and systems in the body are functioning. Now scientists have adapted an emerging biomedical technique to study the vast body of the ocean. In recent work they have demonstrated that they can identify and measure proteins in the ocean, revealing how single-celled marine organisms and ocean ecosystems operate.
Using an "electric prism", or deflector, scientists have found a new way of separating water molecules that differ only in their nuclear spin states and, under normal conditions, do not part ways. Since water is such a fundamental molecule in the universe, the recent study may impact a multitude of research areas ranging from biology to astrophysics.
The taste of common sugar substitutes is often described as being much more intense than sugar, but participants in a recent study indicated that these non-nutritive sugar substitutes are no sweeter than the real thing, according to Penn State food scientists.
Materials made from nanoparticles hold promise for myriad applications. The challenge in creating these wonder materials is organizing the nanoparticles into orderly arrangements. Nanoparticles of magnetite, the most abundant magnetic material on earth, are found in living organisms from bacteria to birds. Nanocrystals of magnetite self-assemble into fine compass needles in the organism that help it to navigate.
A new atomically thin 2-D ultrasensitive semiconductor material developed by researchers California promises to push the boundaries of biosensing technology toward single-molecule detection. Based on molybdenum disulfide or molybdenite, the biosensor material which is used commonly as a dry lubricant, surpasses graphene’s already high sensitivity, offers better scalability and lends itself to high-volume manufacturing.
Scientists’ underwater cameras got a boost this summer from the Electron Microscopy Center at Argonne National Laboratory. Along with colleagues at the Univ. of Manchester, researchers captured the world’s first real-time images and simultaneous chemical analysis of nanostructures while “underwater,” or in solution.
The most familiar photovoltaic (PV) designs use rigid layers of silicon crystal, but recently inexpensive organic semiconductor materials have also been used successfully. At this time, organic PV devices are hindered by low efficiency, in part because quantifying their electrical properties is a challenge. Researchers have now developed a method that allows the prediction of the current density-voltage curve of a photovoltaic device.
Scientists in Switzerland have developed a new amino acid that can be used to modify the 3-D structure of therapeutic peptides. Insertion of the amino acid into bioactive peptides enhanced their binding affinity up to 40-fold. Peptides with the new amino acid could potentially become a new class of therapeutics.
When metallic lithium forms and deposits during the charging process in a lithium-ion battery, it can lead to a reduced battery lifespan and even short circuits. Using neutron beams, scientists have now peered into the inner workings of a functioning battery without destroying it. In the process, they have resolved this so-called lithium plating mystery.
Scientists have tapped oil and water to create scaffolds of self-assembling, synthetic proteins called peptoid nanosheets that mimic complex biological mechanisms and processes. The accomplishmentis expected to fuel an alternative design of the 2-D peptoid nanosheets that can be used in a broad range of applications. Among them could be improved chemical sensors and separators, and safer, more effective drug delivery vehicles.
Researchers working in synthetic organic chemistry are under pressure to quickly develop innovative chemical reactions. But with methods largely unchanged over the last 50 years, synthesis possibilities are constrained by limited temperature ranges, demanding experiment supervision and lack of repeatability. New technology is enhancing synthesis by eliminating these challenges.
In the age-old nature versus nurture debate, Douglas Clark, a faculty scientist with Lawrence Berkeley National Laboratory and the Univ. of California, Berkeley, is not taking sides. In the search for enzymes that can break lignocellulose down into biofuel sugars under the extreme conditions of a refinery, he has prospected for extremophilic microbes and engineered his own cellulases.
A fortuitous collaboration at Rice Univ. has led to the total synthesis of a recently discovered natural antibiotic. The laboratory recreation of a fungus-derived antibiotic, viridicatumtoxin B, may someday help bolster the fight against bacteria that evolve resistance to treatments in hospitals and clinics around the world.
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