Scientists, inspired by a chemical process found in leaves, have developed an electrically conductive film that could help pave the way for devices capable of harnessing sunlight to split water into hydrogen fuel. When applied to semiconducting materials such as silicon, the nickel oxide film prevents rust buildup and facilitates an important chemical process in the solar-driven production of fuels.
Researchers wanted to find a better way to make coatings that can be painted onto surfaces to...
A team of chemical engineering researchers has developed a technique that uses a new catalyst to...
Hydrogen fuel is a promising source of clean energy that can be produced by splitting water into...
The discovery of a new form of ice could lead to an improved understanding of our planet’s geology, potentially helping to unlock new solutions in the production, transportation and storage of energy. Ice XVI, the least dense of all known forms of ice, has a highly symmetric cage-like structure that can trap gaseous molecules to form compounds known as clathrates or gas hydrates.
Hydrogen could be an important source of clean energy, and the cleanest way to produce hydrogen gas is to split water into hydrogen and oxygen. But the catalyst currently used to facilitate this water-splitting reaction is platinum. And that’s a problem.
Large-scale storage of low-pressure, gaseous hydrogen in salt caverns and other underground sites for transportation fuel and grid-scale energy applications offers several advantages over above-ground storage, says a recent Sandia National Laboratories study.
For years, scientists have been pursuing “artificial leaf” technology, a green approach to making hydrogen fuel that copies plants’ ability to convert sunlight into a form of energy they can use. Now, one team reports progress toward a stand-alone system that lends itself to large-scale, low-cost production. They describe their nanowire mesh design in ACS Nano.
Graphene, impermeable to all gases and liquids, can easily allow protons to pass through it, Univ. of Manchester researchers have found. Published in Nature, the discovery could revolutionize fuel cells and other hydrogen-based technologies as they require a barrier that only allow protons to pass through.
Now that car makers have demonstrated through hybrid vehicle success that consumers want less-polluting tailpipes, they are shifting even greener. In 2015, Toyota will roll out the first hydrogen fuel-cell car for personal use that emits only water. An article in Chemical & Engineering Newsexplains how hydrogen could supplant hybrid and electric car technology.
Swedish and Chinese researchers have recently shown how a unique nano-alloy composed of palladium nano-islands embedded in tungsten nanoparticles creates a new type of catalysts for highly efficient oxygen reduction, the most important reaction in hydrogen fuel cells. Their results are published in the scientific journal Nature Communications.
Michael Grätzel’s laboratory in Switzerland is producing hydrogen fuel from sunlight and water. By combining a pair of solar cells made with a mineral called perovskite and low cost electrodes, scientists have obtained a 12.3% conversion efficiency from solar energy to hydrogen, a record using earth-abundant materials as opposed to rare metals.
Researchers at Argonne National Laboratory have created a small scale “hydrogen generator” that uses light and a 2-D graphene platform to boost production of the hard-to-make element. The research also unveiled a previously unknown property of graphene. The 2-D chain of carbon atoms not only gives and receives electrons, but can also transfer them into another substance.
A convergence of factors is propelling a market rollout of the hydrogen fuel cell vehicle, according to a new study. A key to hydrogen’s potential success is a new smart solution that clusters hydrogen fuel infrastructure in urban or regional networks, limiting initial costs and enabling an early market for the technology before committing to a full national deployment.
A research team in Europe has achieved significantly increase in the yield of hydrogen produced by the photocatalytic splitting of water. Their breakthrough in light-driven generation of hydrogen was achieved by using a novel molecular shuttle to enhance charge-carrier transport with semiconductor nanocrystals.
Three automakers plan to begin selling hydrogen-fueled vehicles to consumers in 2015. To support the fair sale of gaseous hydrogen as a vehicle fuel, researchers at NIST have developed a prototype field test standard to test the accuracy of hydrogen fuel dispensers. Once the standard is field tested, it will serve as a model for constructing similar devices for state weights and measures inspectors to use.
Long dismissed as too impractical and expensive for everyday cars, fuel cell technology is getting a push into the mainstream by Toyota, the world's top-selling automaker. Buoyed by its success with electric-gasoline hybrid vehicles, Toyota is betting that drivers will embrace hydrogen fuel cells, an even cleaner technology. The company’s fuel cell car will go on sale before April next year.
Rutgers Univ. researchers have developed a technology that could overcome a major cost barrier to make clean-burning hydrogen fuel. The new catalyst is based on carbon nanotubes and may rival cost-prohibitive platinum for reactions that split water into hydrogen and oxygen.
Turning the “hydrogen economy” concept into a reality, even on a small scale, has been a bumpy road, but scientists are developing a novel way to store hydrogen to smooth out the long-awaited transition away from fossil fuels. Their report on a new solid, stable material that can pack in a large amount of hydrogen that can be used as a fuel appears in Chemistry of Materials.
An international team of researchers have figured out a new way of storing and releasing hydrogen by making a unique crystal phase of a material containing lithium, boron and the key ingredient, hydrogen. To check how they could get the hydrogen back out of the material, the scientists heated it and found that it released hydrogen easily, quickly and only traces of unwanted by-products.
Like a hungry diner ripping open a dinner roll, a fuel cell catalyst that converts hydrogen into electricity must tear open a hydrogen molecule. Now researchers have captured a view of such a catalyst holding onto the two halves of its hydrogen feast. The view confirms previous hypotheses and provides insight into how to make the catalyst work better for alternative energy uses.
Researchers in California have created, for the first time, compounds made from mixtures of calcium hexaboride, strontium and barium hexaboride. They also demonstrated that these ceramic materials could be manufactured using a simple, low-cost manufacturing method known as combustion synthesis.
Porous silicon manufactured in a bottom up procedure using solar energy can be used to generate hydrogen from water, according to a team of Penn State Univ. mechanical engineers, who also see applications for batteries, biosensors and optical electronics as outlets for this new material.
The dream of a hydrogen economy — a world run on H2gas, free from the pollution and politics of fossil fuels — may depend on developing an energy-efficient strategy for splitting water into oxygen and hydrogen. The problem is that water bonds are very stable, requiring hefty energy inputs to break. Scientists are eagerly developing catalysts to lower the energy demands, and thus the cost.
In a recent early online edition of Nature Chemistry, Arizona State Univ. scientists, along with colleagues at Argonne National Laboratory, have reported advances toward perfecting a functional artificial leaf. Designing an artificial leaf that uses solar energy to convert water cheaply and efficiently into hydrogen and oxygen is one of the goals of BISfuel.
Researchers at North Carolina State Univ. have shown that a one-atom thick film of molybdenum sulfide (MoS2) may work as an effective catalyst for creating hydrogen. The work opens a new door for the production of cheap hydrogen. Hydrogen holds great promise as an energy source, but the production of hydrogen from water electrolysis currently relies in large part on the use of expensive platinum catalysts.
Solar energy has long been used as a clean alternative to fossil fuels such as coal and oil, but it could only be harnessed during the day when the sun’s rays were strongest. Now researchers have built a system that converts the sun’s energy not into electricity but hydrogen fuel and stores it for later use, allowing us to power our devices long after the sun goes down.
Researchers in Lyon, a French city famed for its cuisine, have discovered a quick-cook recipe for copious volumes of hydrogen that involves water, rock, aluminum oxide and extreme pressure. The breakthrough suggests a better way of producing the hydrogen that propels rockets and energizes battery-like fuel cells.
Hydrogen is a “green” fuel that burns cleanly and can generate electricity via fuel cells. One way to sustainably produce hydrogen is by splitting water molecules using the renewable power of sunlight, but scientists are still learning how to control and optimize this reaction with catalysts. At the National Synchrotron Light Source, a research group has determined key structural information about a potential catalyst.
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