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Better batteries from waste sulfur

Mon, 04/15/2013 - 8:17am

A University of Arizona-led research team has discovered a simple process for making a new lightweight plastic from the inexpensive and abundant element sulfur. The petri dish on the left contains the plastic. The yellow powder on the right is sulfur. The team has already made a lithium-sulfur battery—the type of next- generation battery that is lighter and cheaper than those currently used in electric and hybrid cars. Image: Jared Griebel/ Pyun laboratory, University of ArizonaA new chemical process can transform waste sulfur into a lightweight plastic that may improve batteries for electric cars, reports a University of Arizona-led team. The new plastic has other potential uses, including optical uses.

The team has successfully used the new plastic to make lithium-sulfur batteries.

"We've developed a new, simple, and useful chemical process to convert sulfur into a useful plastic," lead researcher Jeffrey Pyun says.

Next-generation lithium-sulfur, or Li-S, batteries will be better for electric and hybrid cars and for military uses because they are more efficient, lighter, and cheaper than those currently used, says Pyun, a UA associate professor of chemistry and biochemistry.

The new plastic has great promise as something that can be produced easily and inexpensively on an industrial scale, he says.

The team's discovery could provide a new use for the sulfur left over when oil and natural gas are refined into cleaner-burning fuels.

Although there are some industrial uses for sulfur, the amount generated from refining fossil fuels far outstrips the current need for the element. Some oil refineries, such as those in Ft. McMurray in Alberta, are accumulating yellow mountains of waste sulfur.

"There's so much of it we don't know what to do with it," says Pyun. He calls the left-over sulfur "the garbage of transportation."

About one-half pound of sulfur is left over for every 19 gallons of gasoline produced from fossil fuels, calculates co-author Jared Griebel, a UA chemistry and biochemistry doctoral candidate.

The researchers have filed an international patent for their new chemical process and for the new polymeric electrode materials for Li-S batteries.

The team’s research article is published online in Nature Chemistry.

Pyun wanted to apply his expertise as a chemist to energy-related research. He knew about the world's glut of elemental sulfur at fossil fuel refineries—so he focused on how chemistry could use the cheap sulfur to satisfy the need for good Li-S batteries.

He and his colleagues tried something new: transforming liquid sulfur into a useful plastic that eventually could be produced easily on an industrial scale.

Sulfur poses technical challenges. It doesn't easily form the stable long chains of molecules, known as polymers, needed make a moldable plastic, and most materials don't dissolve in sulfur.

Pyun and his colleagues identified the chemicals most likely to polymerize sulfur and girded themselves for the long process of testing those chemicals one by one by one. More than 20 chemicals were on the list.

They got lucky.

"The first one worked—and nothing else thereafter," Pyun says.

Even though the first experiment worked, the scientists needed to try the other chemicals on their list to see if others worked better and to understand more about working with liquid sulfur.

They've dubbed their process "inverse vulcanization" because it requires mostly sulfur with a small amount of an additive. Vulcanization is the chemical process that makes rubber more durable by adding a small amount of sulfur to rubber.

The new plastic performs better in batteries than elemental sulfur, Pyun says, because batteries with cathodes made of elemental sulfur can be used and recharged only a limited number of times before they fail.

The new plastic has electrochemical properties superior to those of the elemental sulfur now used in Li-S batteries, the researchers report. The team's batteries exhibited high specific capacity (823 mAh/g at 100 cycles) and enhanced capacity retention.

Several companies have expressed interest in the new plastic and the new battery, Pyun says.

The team's next step is comparing properties of the new plastic to existing plastics and exploring other practical applications such as photonics for the new plastic.

Source: University of Arizona

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