Long-wavelength terahertz light is invisible—it's at the farthest end of the far infrared—but it's useful for everything from detecting explosives at the airport, to designing drugs, to diagnosing skin cancer. Now, for the first time, scientists at the U.S. Department of Energy's Lawrence Berkeley National Laboratory (Berkeley Lab) and the University of California at Berkeley have demonstrated a microscale device made of grapheme, whose strong response to light at terahertz frequencies can be tuned with exquisite precision.
"The heart of our device is an array made of graphene ribbons only millionths of a meter wide," says Feng Wang of Berkeley Lab's Materials Sciences Division, who is also an assistant professor of physics at UC Berkeley, and who led the research team. "By varying the width of the ribbons and the concentration of charge carriers in them, we can control the collective oscillations of electrons in the microribbons."
The name for such collective oscillations of electrons is plasmons.
"Plasmons in high-frequency visible light happen in 3D metal nanostructures," Wang says. The colors of medieval stained glass, for example, result from oscillating collections of electrons on the surfaces of nanoparticles of gold, copper, and other metals, and depend on their size and shape. "But graphene is only one atom thick, and its electrons move in only two dimensions. In 2D systems, plasmons occur at much lower frequencies."
The wavelength of terahertz radiation is measured in hundreds of micrometers, yet the width of the graphene ribbons in the experimental device is only one to four micrometers each.
"A material that consists of structures with dimensions much smaller than the relevant wavelength, and which exhibits optical properties distinctly different from the bulk material, is called a metamaterial," says Wang. "So we have not only made the first studies of light and plasmon coupling in graphene, we've also created a prototype for future graphene-based metamaterials in the terahertz range."
The team reports their research in Nature Nanotechnology.
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The strength of the light-plasmon coupling can also be affected by the concentration of charge carriers—electrons and their positively charged counterparts, holes. One remarkable characteristic of graphene is that the concentration of its charge carriers can easily be increased or decreased simply by applying a strong electric field—so-called electrostatic doping.
The Berkeley device incorporates both these methods for tuning the response to terahertz light. Microribbon arrays were made by depositing an atom-thick layer of carbon on a sheet of copper, then transferring the graphene layer to a silicon-oxide substrate and etching ribbon patterns into it. An ion gel with contact points for varying the voltage was placed on top of the graphene.
The gated graphene microarray was illuminated with terahertz radiation at beamline 1.4 of Berkeley Lab's Advanced Light Source, and transmission measurements were made with the beamline’s infrared spectrometer. In this way the research team demonstrated coupling between light and plasmons that was stronger by an order of magnitude than in other 2D systems.
A final method of controlling plasmon strength and terahertz absorption depends on polarization. Light shining in the same direction as the graphene ribbons shows no variations in absorption according to frequency. But light at right angles to the ribbons—the same orientation as the oscillating electron sea—yields sharp absorption peaks. What’s more, light absorption in conventional 2D semiconductor systems, such as quantum wells, can only be measured at temperatures near absolute zero. The Berkeley team measured prominent absorption peaks at room temperature.
"Terahertz radiation covers a spectral range that's difficult to work with, because until now there have been no tools," says Wang. "Now we have the beginnings of a toolset for working in this range, potentially leading to a variety of graphene-based terahertz metamaterials."
The Berkeley experimental setup is only a precursor of devices to come, which will be able to control the polarization and modify the intensity of terahertz light and enable other optical and electronic components, in applications from medical imaging to astronomy—all in two dimensions.SOURCE